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- Normalize the wavefunction for the 2s orbital of a hydrogen electron. 3 Rn. 1 (r) = = (²/7) ² (2 − p) e - ² - a 2Zr na22:39 Wed 14 Dec Question 2 A hydrogen atom is in the n = 55 state. X (b) Calculate the change in energy for a transition from the n = 55 state to the n = 56 state. (c) Calculate the wavelength of the photon that is absorbed in the transition in (b). @ 4% 73. Suppose an electron in a hydrogen atom is in a 2p state, and the radial wavefunction is (2a.)3/2 /3a. 2ao , where a, is the Bohr radius. (a) 2-axis? What possible angles might the angular momentum vector L make with the (b) What is the most probable radius (in terms of a,) at which the electron is found? (c) What is the expectation value of r in this state? Note: xe-"dx = 120. (p) S° x*e-dx = 23.91. What is the probability of finding such an electron between a, and oo? Note:
- An electron is excited from the n=1 ground state to the n=3 state in a hydrogen atom. Which of the following statements are true? Correct the false statements to make them true. (It may help to draw the Bohr model of the atom with the corresponding electron orbits.)a. It takes more energy to ionize (completely remove) the electron from n = 3 than from the ground state.b. The electron is farther from the nucleus on average in the n = 3 state than in the n = 1 state.c. The wavelength of light emitted if the electron drops from n = 3 to n = 2 will be shorter than the wavelength of light emitted if the electron falls from n = 3 to n = 1.d. The wavelength of light emitted when the electron returns to the ground state from n = 3 will be the same as the wavelength of light absorbed to go from n = 1 to n = 3.e. For n = 3, the electron is in the first excited state.3. Suppose an electron in a hydrogen atom is in a 2p state, and the radial wavefunction e 2ao, where a, is the Bohr radius. 1 is (2ао)3/2 VЗа. (а) What possible angles might the angular momentum vector L make with the Z-axis? (b) What is the most probable radius (in terms of a.) at which the electron is found? (c) What is the expectation value of r in this state? Note: S xe-"dx 120. (d) What is the probability of finding such an electron between a, and ∞? Note: ° x*e-"dx = 23.91.Schematic of the n=3 → n=2 transitions that may occur when a hydrogen atom is placed in a magnetic field B. Ignore the effect of electron spin.
- 2. Consider the states of hydrogen atom given by (n, l, m) where n a. What is the maximum value of l? If L² is measured what is the maximum possible value that can be obtained? b. What is the maximum value of L₂?what energy is required to remove the electron from a hydrogen atom in the n= 11 state? Let the constant hcR= 13.6 eV11. The Hamiltonian for an electron in a hydrogen atom subject to a constant magnetic field B is given by H = e2 p² 2me Απεργ e + (L+2S). B 2me where L and S are the angular momentum and spin operators respectivelyr. Assume the magnetic field points in the z-direction. (a) How many distinct energy levels will the n = : 3 state have? = = 3,1 = 2) → (n = 2,1 = 1). Find the energy of the (b) Consider the line corresponding to the transition (n emitted photons (hw AE, with AE = the energy difference between initial and final state), assuming the possible transitions are constrained by the selection rule Am = 0,±1.