### Organic Chemistry Fill-in-the-Blank Exercise#### Problem 2:**Fill-in-the-blank:** Draw the reagents or the major organic product(s) for each reaction in the boxes provided. Stereochemistry should be shown if applicable.---1. **Reaction 1:** - **Substrate:** An alkene with a phenyl group. - **Reagent:** HBr - **Box:** Draw the major organic product resulting from the reaction of the given alkene with HBr.2. **Reaction 2:** - **Substrate:** Naphthalene - **Reagent:** KMnO₄, NaOH (cold) - **Box:** Draw the major organic product resulting from the reaction of naphthalene with the reagents under cold conditions.3. **Reaction 3:** - **Substrate:** Benzene with a COCH₃ group - **Product:** Acetophenone - **Box:** Identify and draw the missing reactant(s) necessary to produce the given product.*Note: Ensure to depict any stereochemistry in the resulting products as applicable.*

First reaction leads to produce secondary carbocation which rearranges to form stable tertiary carbocation which leads to produce products. Second reaction involves cis diol formation and dicarboxylic acid compound. Third reaction need O3 / Me2S for C=C bond breaking to form dicarbonyl compound.

Answered: 2. Fill-in-the-blank: Draw the reagents…

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2. Fill-in-the-blank: Draw the reagents or the major organic product(s) for each reaction in the boxes provided. Stereochemistry should be shown if applicable. HBr KMnO4, NaOH cold

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Reactions of Ethers

Ethers (R-O-R’) are compounds formed by replacing hydrogen atoms of an alcohol (R-OH compound) or a phenol (C6H5OH) by an aryl/ acyl group (functional group after removing single hydrogen from an aromatic ring). In this section, reaction, preparation and behavior of ethers are discussed in the context of organic chemistry.

Epoxides

Epoxides are a special class of cyclic ethers which are an important functional group in organic chemistry and generate reactive centers due to their unusual high reactivity. Due to their high reactivity, epoxides are considered to be toxic and mutagenic.

Williamson Ether Synthesis

An organic reaction in which an organohalide and a deprotonated alcohol forms ether is known as Williamson ether synthesis. Alexander Williamson developed the Williamson ether synthesis in 1850. The formation of ether in this synthesis is an SN2 reaction.

Question

### Organic Chemistry Fill-in-the-Blank Exercise

#### Problem 2:
**Fill-in-the-blank:** Draw the reagents or the major organic product(s) for each reaction in the boxes provided. Stereochemistry should be shown if applicable.

---

1. **Reaction 1:**

- **Substrate:** An alkene with a phenyl group.
- **Reagent:** HBr
- **Box:** Draw the major organic product resulting from the reaction of the given alkene with HBr.

2. **Reaction 2:**

- **Substrate:** Naphthalene
- **Reagent:** KMnO₄, NaOH (cold)
- **Box:** Draw the major organic product resulting from the reaction of naphthalene with the reagents under cold conditions.

3. **Reaction 3:**

- **Substrate:** Benzene with a COCH₃ group
- **Product:** Acetophenone
- **Box:** Identify and draw the missing reactant(s) necessary to produce the given product.

*Note: Ensure to depict any stereochemistry in the resulting products as applicable.*

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