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- 4-methyl-3-hexanol was prepared by reacting an alkene with either hydroboration-oxidation or oxymercuration-reduction. Draw the structure of the alkene that was used to prepare the alcohol in highest yield. • You do not have to consider stereochemistry. • Indicate the method of preparation by drawing either BH3 (for . If there is more than one alkene that can be used for a given method, draw all of them. If either hydroboration-oxidation or oxymercuration-reduction can be used, just give the structures for one method. Separate structures with + signs from the drop-down menu. ● 981 -- 26224 ? ChemDoodle Y hydroboration-oxidation), or Hg (for oxymercuration-reduction), in a separate sketcher. Sn [12. Why do 1-methylcyclohexene and 3-methylcyclohexene have a lower boiling point than 2-methylcyclohexanol?1. Explain why 5,6-dichlorocyclohexene is an incorrect name for that compound. 2. Explain why 1,1-dimethylethene is an incorrect name for that compound.
- 1. Write the overall reaction for an El reaction or the dehydration of an alcohol.Give the correct IUPAC name of the following compound: ... A 7-cyclohexyl-3,5,5-trimethyl-4-pentylheptane B 1-cyclohexyl-4-sec-butyl-3,3-dimethylnonane 1-cyclohexyl-3,3,5-trimethyl-4-pentylheptane D 4-sec-butyl-1-cyclohexyl-3,3-dimethylnonane E none of thesea) Give the molecular formula and draw the skeletal structure for 3-bromo-3- methylhexane. b) Name (including E/Z stereochemistry) the FIVE alkenes that can produce 3-bromo-3- methylhexane on reaction with HBr. Draw the skeletal structure of each molecule.??? c) Define the type of stereoisomerism present in 3-bromo-3-methylhexane. Name and draw the tetrahedral representation of the two stereoisomers?. d) For the base-catalysed hydrolysis of 3-bromo-3-methylhexane (i.e. reaction with the nucleophile OH-): i) ii) iii) iv) State whether the reaction is likely to proceed by an SN1 or SN2 mechanism, and explain your choice Give the likely rate law for the reaction. Explain your choice. For the reaction intermediate, draw its structure and give the VSEPR description of the geometry at the reaction centre Give the names and draw the structures of the two reaction products. Explain your conclusions
- Please provide detailed solution and give the explanation of correct and incorrect options....1. a secondary alkyl halide with molecular formula C4H9l 2. trans-1,2-cyclopentanediol 3. tert-butyl phenyl ether 4. an ether with molecular formula C3H8O 5. p-aminophenol2. The molecules shown below are four terpineol isomers. They are isolated from plants and have distinct aromas. For example, a -terpineol is a common perfume ingredient and smells similar to lilacs. Hol H-O- a-terpineol B-terpineol Y-terpineol 4-terpineol A) Draw a structural isomer of terpineol that meet the following criteria. You should draw one unique structure for each set. You must draw each molecule twice, once as a skeletal structure and once as a complete Lewis structure showing all atoms, bonds, and lone pairs of electrons. i. Does not have a ring. ii. Has an E alkene. iii. Has a secondary alcohol. iv. Does not contain an alcohol. B) Draw a complete Lewis structure of a-terpineol showing all bonds, atoms and lone pairs of electrons.
- Why is a substituted cyclohexane ring more stable with a larger group in the equatorial position?1. Draw structural formulas for 1-bromobutane, 2-bromobutane, 2-bromo-2- methylpropane, 1-bromo-2-methylpropane, and 1-bromo-2,2-dimethylpropane. Classify each compound as a primary halide, secondary halide, or tertiary halide. 2. Draw structural formulas for acetone and ethanol. Which solvent is more polar? Explain. 3. A student wishes to determine the rate law for the reaction A +B → C. The student doubles the concentration of A while holding the concentration of B constant and finds that the rate of the reaction doubles. The student then doubles the concentration of B while holding the concentration of A constant and finds that the rate is unchanged. Write the rate law for this reaction. (Refer to a general chemistry text, if necessary.) Experimental Procedure S a10) For the reaction between isopropyl 1-propyl (or 'n-propyl') ether and HBr, which type of reaction best matches the expected products? A) Acid-catalyzed dehydration B) Nucleophilic substitution reaction C) Ether cleavage reaction D) Nucleophilic addition-elimination reaction