2. Do the following synthesis: (a) Benzene to 1-t-butyl-3-ethylbenzene (b) Benzene to m-bromobenzoic acid (c) Benzene to Benzene-1,3-dicarboxylic acid

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2. Do the following synthesis:
(a) Benzene to 1-t-butyl-3-ethylbenzene
(b) Benzene to m-bromobenzoic acid
(c) Benzene to Benzene-1,3-dicarboxylic acid
(d) Benzene to p-t-butylbenzoic acid
(e) Benzene to 1,3-dipropylbenzene
(f) Benzene to p-nitrobenzoic acid
(g) Benzene to p-bromobenzaldehyde
(h) Acetophenone to 1,3-diethylbenzene
Transcribed Image Text:2. Do the following synthesis: (a) Benzene to 1-t-butyl-3-ethylbenzene (b) Benzene to m-bromobenzoic acid (c) Benzene to Benzene-1,3-dicarboxylic acid (d) Benzene to p-t-butylbenzoic acid (e) Benzene to 1,3-dipropylbenzene (f) Benzene to p-nitrobenzoic acid (g) Benzene to p-bromobenzaldehyde (h) Acetophenone to 1,3-diethylbenzene
3. What is the main product for each of the following reactions?
(a) p-Methylanisole + CH3CH₂COCI, AICI3
-> ?
(b) Toluene + Br₂, light, then CH3CH₂COCI, AICI 3
-> ?
-> ?
(c) Acetophenone + CH³CH₂CI, AICI3, then Br₂, Fe -----> ?
(d) Styrene + CH3CH₂COCI AICI3, then Br2, Fe
(e) Benzene + 1-chloro-2,2-dimethylpropane, AlCl3 ----> ?
(f) Benzene + 3-phenyl-1-propene, H₂SO4, heat > ?
(g) Toluene + 1-phenyl-3,3-dimethyl-2-butanol, H₂SO4, heat
(h) Benzene + HCOCI, AICI3 then 1-chlorobutane, AlCl3 - ?
‒‒‒‒
Transcribed Image Text:3. What is the main product for each of the following reactions? (a) p-Methylanisole + CH3CH₂COCI, AICI3 -> ? (b) Toluene + Br₂, light, then CH3CH₂COCI, AICI 3 -> ? -> ? (c) Acetophenone + CH³CH₂CI, AICI3, then Br₂, Fe -----> ? (d) Styrene + CH3CH₂COCI AICI3, then Br2, Fe (e) Benzene + 1-chloro-2,2-dimethylpropane, AlCl3 ----> ? (f) Benzene + 3-phenyl-1-propene, H₂SO4, heat > ? (g) Toluene + 1-phenyl-3,3-dimethyl-2-butanol, H₂SO4, heat (h) Benzene + HCOCI, AICI3 then 1-chlorobutane, AlCl3 - ? ‒‒‒‒
Expert Solution
Step 1

Benzene shows an electrophilic substitution reaction because to retain the aromaticity. Monosubstituted benzene further substitution direct by the nature of substituent.  

 

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