2., Bond H-H H-C H-N H-O H-F C-O H-Cl C-C Using the bond energy table below, estimate the DH value for each reaction. Bond Energy (kJ/mole) 436 414 389 464 569 351 431 347 ->> a. 4CH3NH2 + 902 4CO2+ 10H₂O + 2N₂ b. N₂H4 + 2HCl → N₂H₂Cl₂ + 2H₂ N2H2Cl2 Bond N-N 0 0 Cl-Cl C=O N=O 0=0 C=C N=N c. N₂H4 + 2H₂O2 → N₂ + 4H₂O -> Bond Energy (kJ/mole) 159 138 243 803 631 498 837 946 C-N = 290 kJ/mol N-C1= 200 kJ/mol
Electronic Effects
The effect of electrons that are located in the chemical bonds within the atoms of the molecule is termed an electronic effect. The electronic effect is also explained as the effect through which the reactivity of the compound in one portion is controlled by the electron repulsion or attraction producing in another portion of the molecule.
Drawing Resonance Forms
In organic chemistry, resonance may be a mental exercise that illustrates the delocalization of electrons inside molecules within the valence bond theory of octet bonding. It entails creating several Lewis structures that, when combined, reflect the molecule's entire electronic structure. One Lewis diagram cannot explain the bonding (lone pair, double bond, octet) elaborately. A hybrid describes a combination of possible resonance structures that represents the entire delocalization of electrons within the molecule.
Using Molecular Structure To Predict Equilibrium
Equilibrium does not always imply an equal presence of reactants and products. This signifies that the reaction reaches a point when reactant and product quantities remain constant as the rate of forward and backward reaction is the same. Molecular structures of various compounds can help in predicting equilibrium.
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