2. Although models cannot show this simply, for molecules like NF3 (whose Lewis structure you drew on the previous page), the actual bond angles may not exactly equal the angles predicted by VSEPR theory. For example, the F-N-F bond angles in NF3 are less than the 109.5° tetrahedral angle. Why do you think this might be so?

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### Exploring Molecular Geometry: NF₃ Bond Angles

**2. Investigation into NF₃ Bond Angles**

In molecular geometry, while theoretical models provide a fundamental understanding, they often don't capture the intricacies of specific molecules. Take for example, NF₃ (nitrogen trifluoride); despite the Lewis structure illustrating ideal bond angles, real-world measurements can differ. 

The predicted bond angles based on VSEPR (Valence Shell Electron Pair Repulsion) theory typically suggest a tetrahedral angle of 109.5°. However, in the case of NF₃, the actual F–N–F bond angles are less than this. 

**Question:** Why might this discrepancy occur?

---

**Key Considerations:**

- **Electron Pair Repulsion:** The presence of a lone pair on nitrogen affects bond angles, typically compressing the F–N–F bond angle.
  
- **Real-world Influences:** Factors such as electron cloud distortions and differences in atomic sizes can lead to deviations from theoretical predictions.

Understanding these nuances helps us appreciate the complexity of molecular shapes and behaviors in chemistry.
Transcribed Image Text:### Exploring Molecular Geometry: NF₃ Bond Angles **2. Investigation into NF₃ Bond Angles** In molecular geometry, while theoretical models provide a fundamental understanding, they often don't capture the intricacies of specific molecules. Take for example, NF₃ (nitrogen trifluoride); despite the Lewis structure illustrating ideal bond angles, real-world measurements can differ. The predicted bond angles based on VSEPR (Valence Shell Electron Pair Repulsion) theory typically suggest a tetrahedral angle of 109.5°. However, in the case of NF₃, the actual F–N–F bond angles are less than this. **Question:** Why might this discrepancy occur? --- **Key Considerations:** - **Electron Pair Repulsion:** The presence of a lone pair on nitrogen affects bond angles, typically compressing the F–N–F bond angle. - **Real-world Influences:** Factors such as electron cloud distortions and differences in atomic sizes can lead to deviations from theoretical predictions. Understanding these nuances helps us appreciate the complexity of molecular shapes and behaviors in chemistry.
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