2. A stoichiometric mixture of elemental boron and graphite is processed to form a compact which is ignited in an SHS (Self-propagating High-temperature Synthesis) reaction to produce boron carbide (B4C). The reaction is: 4 B (s) + C (s) = B.C (s)

Introduction to Chemical Engineering Thermodynamics
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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2. A stoichiometric mixture of elemental boron and graphite is processed to form a compact which is
ignited in an SHS (Self-propagating High-temperature Synthesis) reaction to produce boron carbide
(B4C). The reaction is:
4 B (s) + C (s) = B.C (s)
a) If the compact (the mixture of B and C) is initially at 298 K, what is the temperature boron carbide
could attain when the reaction is adiabatic?
b) Calculate entropy change of the process.
Cp = a +bT + cT² (J/mol.K)
AH°298
(J/mole)
S°298
bx 103
cx 10-5
a
(J/mole.K)
C (s)
6.
17
...
B (s)
16
...
BẠC (s)
- 63000
27
96
Transcribed Image Text:2. A stoichiometric mixture of elemental boron and graphite is processed to form a compact which is ignited in an SHS (Self-propagating High-temperature Synthesis) reaction to produce boron carbide (B4C). The reaction is: 4 B (s) + C (s) = B.C (s) a) If the compact (the mixture of B and C) is initially at 298 K, what is the temperature boron carbide could attain when the reaction is adiabatic? b) Calculate entropy change of the process. Cp = a +bT + cT² (J/mol.K) AH°298 (J/mole) S°298 bx 103 cx 10-5 a (J/mole.K) C (s) 6. 17 ... B (s) 16 ... BẠC (s) - 63000 27 96
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