2+ Kidney stones can be indicated, in part, by elevated levels of calcium in urine. Ca is precipitated as CaC204 H20, filtered, washed, and titrated with standardized KMnO4 according to the reaction: 2 MnO4 + 16 H+ + 5 C2042-→ 2 Mn2+ +8 H2O + 10 CO2. A clinical technician obtained a 5.00-mL sample of urine from a patient. The calcium in urine was precipitated out as calcium oxalate, CaC204, and then subsquently dissolved in acid. The resultant mixture required 8.80 mL of 1.617 x 10 M KMnO4 to reach the colorless-to-pink end point. In correct significant figures, the molar concentration of Ca2+ in the urine sample is 7.115 X 10E-3 [NOTE: Just write the number. If your answer is 1.2345 x 10-67, use the format: 1.2345 x 10E-67. There is a space before and after the x.]

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter17: Principles Of Chemical Reactivity: Other Aspects Of Aqueous Equilibria
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Problem 103IL: The cations Ba2+ and Sr2+ can be precipitated as very insoluble sulfates. (a) If you add sodium...
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Kidney stones can be indicated, in part, by elevated levels of calcium in urine. Ca is precipitated as
CaC204 H20, filtered, washed, and titrated with standardized KMnO4 according to the reaction:
2 MnO4 + 16 H+ + 5 C2042-→ 2 Mn2+ +8 H2O + 10 CO2.
A clinical technician obtained a 5.00-mL sample of urine from a patient. The calcium in urine was
precipitated out as calcium oxalate, CaC204, and then subsquently dissolved in acid. The resultant
mixture required 8.80 mL of 1.617 x 10 M KMnO4 to reach the colorless-to-pink end point.
In correct significant figures, the molar concentration of Ca2+ in the urine sample is 7.115 X 10E-3
[NOTE: Just write the number. If your answer is 1.2345 x 10-67, use the format: 1.2345 x 10E-67. There
is a space before and after the x.]
Transcribed Image Text:2+ Kidney stones can be indicated, in part, by elevated levels of calcium in urine. Ca is precipitated as CaC204 H20, filtered, washed, and titrated with standardized KMnO4 according to the reaction: 2 MnO4 + 16 H+ + 5 C2042-→ 2 Mn2+ +8 H2O + 10 CO2. A clinical technician obtained a 5.00-mL sample of urine from a patient. The calcium in urine was precipitated out as calcium oxalate, CaC204, and then subsquently dissolved in acid. The resultant mixture required 8.80 mL of 1.617 x 10 M KMnO4 to reach the colorless-to-pink end point. In correct significant figures, the molar concentration of Ca2+ in the urine sample is 7.115 X 10E-3 [NOTE: Just write the number. If your answer is 1.2345 x 10-67, use the format: 1.2345 x 10E-67. There is a space before and after the x.]
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