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2) Given the following reaction mechanism, 2 NO₂CICIO₂ + N₂O + CIO (fast equilibrium) k-1 N₂O + CIO₂ NO₂ NO₂ + NOCI (fast equilibrium) NOCI k3 CIO ³ NO₂ + Cl₂ (slow) a) What is the overall reaction? b) List the intermediate(s) in the reaction. c) Derive the rate law and indicate the order of reaction with respect to NO₂. PM PM PM

2) Given the following reaction mechanism, 2 NO₂CICIO₂ + N₂O + CIO (fast equilibrium) k-1 N₂O + CIO₂ NO₂ NO₂ + NOCI (fast equilibrium) NOCI k3 CIO ³ NO₂ + Cl₂ (slow) a) What is the overall reaction? b) List the intermediate(s) in the reaction. c) Derive the rate law and indicate the order of reaction with respect to NO₂. PM PM PM

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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2) Given the following reaction mechanism, 2 NO₂CICIO₂ + N₂O + CIO (fast equilibrium) k-1 N₂O + CIO₂ NO₂ NO₂ + NOCI (fast equilibrium) NOCI k3 CIO ³ NO₂ + Cl₂ (slow) a) What is the overall reaction? b) List the intermediate(s) in the reaction. c) Derive the rate law and indicate the order of reaction with respect to NO₂. PM PM PM
Transcribed Image Text:2) Given the following reaction mechanism, 2 NO₂CICIO₂ + N₂O + CIO (fast equilibrium) k-1 N₂O + CIO₂ NO₂ NO₂ + NOCI (fast equilibrium) NOCI k3 CIO ³ NO₂ + Cl₂ (slow) a) What is the overall reaction? b) List the intermediate(s) in the reaction. c) Derive the rate law and indicate the order of reaction with respect to NO₂. PM PM PM
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