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- The phosphorus trihalides 1PX32 show the following variationin the bond angle X¬P¬X: PF3, 96.3°; PCl3, 100.3°;PBr3, 101.0°; PI3, 102.0°. The trend is generally attributedto the change in the electronegativity of the halogen.(a) Assuming that all electron domains are the same size,what value of the X¬P¬X angle is predicted by the VSEPRmodel? (b) What is the general trend in the X¬P¬Xangle as the halide electronegativity increases? (c) Usingthe VSEPR model, explain the observed trend in X¬P¬Xangle as the electronegativity of X changes. (d) Based onyour answer to part (c), predict the structure of PBrCl4.Consider a molecule with formula AX3. Supposing the A¬Xbond is polar, how would you expect the dipole moment ofthe AX3 molecule to change as the X¬A¬X bond angle increasesfrom 100° to 120°?Consider the molecule C4H5N, which has the connectivityshown below. (a) After the Lewis structure for the moleculeis completed, how many s and how many p bonds arethere in this molecule? (b) How many atoms in the moleculeexhibit (i) sp hybridization, (ii) sp2 hybridization, and(iii) sp3 hybridization?
- A benzene molecule can be modeled as six carbon atoms arrangedin a regular hexagon in a plane. At each carbon atom, one of threeradicals NH2, COOH, or OH can be attached. How many suchcompounds are possible? (Make no distinction between single anddouble bonds between the atoms.)The compound 2,6-dimethylpyrazine (below) gives chocolate its odor and is used in flavorings. (a) Which atomic orbitals mix to form the hybrid orbitals of N? (b) In what type of hybrid orbital do the lone pairs of N reside? (c) Is C in CH3 hybridized the same as any C in the ring? Explain.Ethyl acetate, C4H8O2, is a fragrant substance used both as asolvent and as an aroma enhancer. Its Lewis structure is (a) What is the hybridization at each of the carbon atomsof the molecule? (b) What is the total number of valenceelectrons in ethyl acetate? (c) How many of the valence electronsare used to make s bonds in the molecule? (d) Howmany valence electrons are used to make p bonds? (e) Howmany valence electrons remain in nonbonding pairs in themolecule?
- Acetylsalicylic acid, better known as aspirin, has the Lewisstructure (a) What are the approximate values of the bond angles labeled1, 2, and 3? (b) What hybrid orbitals are used about thecentral atom of each of these angles? (c) How many s bondsare in the molecule?Enter in order the abbreviations for the electron geometry (EG) and the hybridization of the central atom for each substance.Consider the molecule PS3-1. Whatarethe angles of the P-S bonds?
- Identify the likely structure dipole moment of the theoretical molecule C(OH)3Cl. Provide a hand-drawn illustration showing the molecule's 3D structure and dipole moment if applicable.(a) Complete the Lewis structure for the molecule shown below. How many lone pairs are there? H-C H 1 H (b) Give the hybridizations of the following atoms in the structure: (i) Ca; (ii) Ob (c) Give approximate values of the following bond angles: (i) O a-Ca-Ob; (ii) С a -О b-СbThe diagram that follows shows the highest-energy occupiedMOs of a neutral molecule CX, where element X is in thesame row of the periodic table as C. (a) Based on the numberof electrons, can you determine the identity of X? (b) Wouldthe molecule be diamagnetic or paramagnetic? (c) Considerthe p2p MOs of the molecule. Would you expect them to havea greater atomic orbital contribution from C, have a greateratomic orbital contribution from X, or be an equal mixtureof atomic orbitals from the two atoms?
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