2- Consider a solution of an electrolyte that is completely dissociated into ions. By the additivity rule the Gibbs energy of the solution should be the sum of the Gibbs energies of the solvent, the positive and the negative ions: Using the following equations: Gnsμs + n + μ + + n_μ. Prove that a = a = μμ°RT In a; = HμRT In a+ H+μRT In a+ μ_=μ+RT In a
2- Consider a solution of an electrolyte that is completely dissociated into ions. By the additivity rule the Gibbs energy of the solution should be the sum of the Gibbs energies of the solvent, the positive and the negative ions: Using the following equations: Gnsμs + n + μ + + n_μ. Prove that a = a = μμ°RT In a; = HμRT In a+ H+μRT In a+ μ_=μ+RT In a
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:2- Consider a solution of an electrolyte that is completely dissociated into ions. By the additivity rule
the Gibbs energy of the solution should be the sum of the Gibbs energies of the solvent, the positive
and the negative ions:
Using the following equations:
Gnsμs + n + μ + + n_μ.
Prove that a = a
=
μμ°RT In a;
=
HμRT In a+
H+μRT In a+
μ_=μ+RT In a
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