1)Which substance has the higher entropy?a) dry ice (solid CO2) at –78 OC or CO2(g) at 0 OCb) liquid water at 25 OC or liquid water at 50 OCc) pure alumina, Al2O3(s), or ruby (ruby is Al2O3 in which some Al3+ ions in the crystalline lattice are replaced with Cr3+ ions)d) one mole of N2(g) at 1 bar pressure or one mole of N2(g) at 10 bar pressure (both at 298 K)
1)Which substance has the higher entropy?a) dry ice (solid CO2) at –78 OC or CO2(g) at 0 OCb) liquid water at 25 OC or liquid water at 50 OCc) pure alumina, Al2O3(s), or ruby (ruby is Al2O3 in which some Al3+ ions in the crystalline lattice are replaced with Cr3+ ions)d) one mole of N2(g) at 1 bar pressure or one mole of N2(g) at 10 bar pressure (both at 298 K)
General Chemistry - Standalone book (MindTap Course List)
11th Edition
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Chapter18: Thermodynamics And Equilibrium
Section: Chapter Questions
Problem 18.2QP: Which contains greater entropy, a quantity of frozen benzene or the same quantity of liquid benzene...
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1)Which substance has the higher entropy?a) dry ice (solid CO2) at –78 OC or CO2(g) at 0 OCb) liquid water at 25 OC or liquid water at 50 OCc) pure alumina, Al2O3(s), or ruby (ruby is Al2O3 in which some Al3+ ions in the crystalline lattice are replaced with Cr3+ ions)d) one mole of N2(g) at 1 bar pressure or one mole of N2(g) at 10 bar pressure (both at 298 K)
Expert Solution
Step 1
1. CO2(g) at 0oC has higher entropy than dry ice at -78oC, because gas has higher entropy due to its high disorderness.
2. Liquid water at 50oC has higher entropy than water at 25oC, as increase in temperature increases randomness.
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