Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter22: Organic Chemistry And Biochemistry
Section: Chapter Questions
Problem 31QE
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#19

The following IUPAC name is incorrect. Explain why it is incorrect and give the correct IUPAC name.
2,2-dimethyl-4-ethylheptane
The compound has incorrectly labeled
substituents.
The compound name is alphabetized
incorrectly.
The compound has an incorrectly labeled
parent chain.
The compound name is spelled
incorrectly.
Which of the following is the correct IUPAC name?
○ 4-ethyl-6,6-dimethylheptane ○ 2,2-dimethyl-4-propylhexane
3-propyl-5,5-dimethylhexane 4-ethyl-2,2-dimethylheptane
Transcribed Image Text:The following IUPAC name is incorrect. Explain why it is incorrect and give the correct IUPAC name. 2,2-dimethyl-4-ethylheptane The compound has incorrectly labeled substituents. The compound name is alphabetized incorrectly. The compound has an incorrectly labeled parent chain. The compound name is spelled incorrectly. Which of the following is the correct IUPAC name? ○ 4-ethyl-6,6-dimethylheptane ○ 2,2-dimethyl-4-propylhexane 3-propyl-5,5-dimethylhexane 4-ethyl-2,2-dimethylheptane
Expert Solution
Step 1: IUPAC nomenclature rules

IUPAC nomenclature is used for the systematic naming of organic molecules.
According to IUPAC nomenclature select the longest chain of hydrocarbon which contains the maximum number of carbon atoms consider this is a parent hydrocarbon.
Number the carbon in such a way that substituents get the lower number. 

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