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18. Draw the two products that you expect in each of the following SN1 reaction and describe their stereoisomeric relationship: Br NaSH

18. Draw the two products that you expect in each of the following SN1 reaction and describe their stereoisomeric relationship: Br NaSH

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**18. Draw the two products that you expect in each of the following SN1 reaction and describe their stereoisomeric relationship:** **Diagram Explanation:** The diagram shows a chemical reaction involving a structural formula. On the left side, there is a molecule with a bromine (Br) atom attached to a carbon chain. The bromine is shown with a wedge indicating its stereochemistry. The carbon chain includes other groups such as methyl groups. The reaction arrow indicates the use of sodium hydrosulfide (NaSH) as a reagent, leading to an expected transformation of the molecule. **Expected Outcome Description:** In this SN1 reaction, the bromine atom will be replaced by a sulfhydryl group (SH) due to the action of NaSH. Two stereoisomers are expected as products due to the formation of a carbocation intermediate, which can lead to a racemic mixture. This means that the reaction products will consist of both enantiomers, which are mirror images of each other, and exhibit different stereochemistry at the reactive center. The relationship between the two products will be that of enantiomers.
Transcribed Image Text:**18. Draw the two products that you expect in each of the following SN1 reaction and describe their stereoisomeric relationship:** **Diagram Explanation:** The diagram shows a chemical reaction involving a structural formula. On the left side, there is a molecule with a bromine (Br) atom attached to a carbon chain. The bromine is shown with a wedge indicating its stereochemistry. The carbon chain includes other groups such as methyl groups. The reaction arrow indicates the use of sodium hydrosulfide (NaSH) as a reagent, leading to an expected transformation of the molecule. **Expected Outcome Description:** In this SN1 reaction, the bromine atom will be replaced by a sulfhydryl group (SH) due to the action of NaSH. Two stereoisomers are expected as products due to the formation of a carbocation intermediate, which can lead to a racemic mixture. This means that the reaction products will consist of both enantiomers, which are mirror images of each other, and exhibit different stereochemistry at the reactive center. The relationship between the two products will be that of enantiomers.
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