18- Consider the following reaction that occurs in the atmosphere on a smoggy day: NO + 03) NO₂(g) + 0₂ (8) r = k[NO] Which of the following mechanisms is consistent with this rate law? Explain. a) NO 03 NO₂ + 0₂ (slow) b) NO N+ 0₂ 0 + 0 NO + c) 03 0₂ O + NO NO + 0₂ N+O NO₂ + O 0₂ NO₂ + 0₂ 0₂ + 0 NO₂ NO₂ + 0₂ (slow) (fast) (fast) (overall) (slow) (fast) (overall)

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18- Consider the following reaction that occurs in the atmosphere on a smoggy day:
NO(g) + 03 (8)
NO2(g) +
0₂ (8)
r=k[NO]
Which of the following mechanisms is consistent with this rate law? Explain.
a) NO
+
03
NO₂ +
0₂ (slow)
b)
NO
N + 03
0 + 0
NO +
c)
0₂
0+ NO
NO + 0₂
N+O
NO₂ + O
0₂
NO₂ + 0₂
0₂ + 0
NO₂
NO₂ + 0₂
(slow)
(fast)
(fast)
(overall)
(slow)
(fast)
(overall)
Transcribed Image Text:18- Consider the following reaction that occurs in the atmosphere on a smoggy day: NO(g) + 03 (8) NO2(g) + 0₂ (8) r=k[NO] Which of the following mechanisms is consistent with this rate law? Explain. a) NO + 03 NO₂ + 0₂ (slow) b) NO N + 03 0 + 0 NO + c) 0₂ 0+ NO NO + 0₂ N+O NO₂ + O 0₂ NO₂ + 0₂ 0₂ + 0 NO₂ NO₂ + 0₂ (slow) (fast) (fast) (overall) (slow) (fast) (overall)
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