Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![A reaction A → B has the following time dependence for the concentration of [A] vs time. For t=(0 s, 5 s, 10 s, 15 s, 25 s) the concentration
of [A]=(30.00 M, 17.75 M, 12.61 M, 9.77 M, 6.74 M). The initial concentration of [A] is the value at t=0 s.
(A)Calculate the values of the rate constant k assuming that the reaction is first order.
What is the value of k at 5 s? 0.105
What is the value of k at 10 s? 0.087
What is the value of k at 15 s? 0.0748
What is the value of k at 25 s? 0.0597
(B)Calculate the value of k assuming that the reaction is second order.
M-¹5-1
What is the value of k at 5 s? 0.0046
What is the value of k at 10 s? 0.00459
What is the value of k at 15 s? 0.00460
0.00460
What is the value of k at 25 s?
S-1
$1
S-1
M-15-1
M-15-1
M-15-1
(C)Use your results from parts A and B above to decide what the order of the reaction is for your data. (Enter 1 or 2) 2
(D)What is the concentration of [A] at time t=64 s? 2.81
XM](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F86624ab7-da2a-4a5b-91b8-0bf4ad8ab366%2F3d3dc7c3-c883-4b88-9b38-f61f57cdcab6%2Fld53cfj_processed.png&w=3840&q=75)
Transcribed Image Text:A reaction A → B has the following time dependence for the concentration of [A] vs time. For t=(0 s, 5 s, 10 s, 15 s, 25 s) the concentration
of [A]=(30.00 M, 17.75 M, 12.61 M, 9.77 M, 6.74 M). The initial concentration of [A] is the value at t=0 s.
(A)Calculate the values of the rate constant k assuming that the reaction is first order.
What is the value of k at 5 s? 0.105
What is the value of k at 10 s? 0.087
What is the value of k at 15 s? 0.0748
What is the value of k at 25 s? 0.0597
(B)Calculate the value of k assuming that the reaction is second order.
M-¹5-1
What is the value of k at 5 s? 0.0046
What is the value of k at 10 s? 0.00459
What is the value of k at 15 s? 0.00460
0.00460
What is the value of k at 25 s?
S-1
$1
S-1
M-15-1
M-15-1
M-15-1
(C)Use your results from parts A and B above to decide what the order of the reaction is for your data. (Enter 1 or 2) 2
(D)What is the concentration of [A] at time t=64 s? 2.81
XM
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