16.59 A proposed mechanism for the reaction of carbon dioxide with hydroxide ion in aqueous solution is (1) СО,(ад) + ОН (аq) —> НСО, (аq) (2) HCO,-(aq) + OH¯(aq) → CO,²-(aq) + H,O(1) [fast] [slow] (a) What is the overall equation? (b) Identify the reaction intermediate(s), if any. (c) What are the molecularity and the rate law for each step? (d) Is the mechanism consistent with the actual rate law: k[CO,][OH¯]? rate

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16.59 A proposed mechanism for the reaction of carbon dioxide
with hydroxide ion in aqueous solution is
(1) СО,(ад) + ОН (аq) —> НСО, (аq)
(2) HCO,-(aq) + OH¯(aq) → CO,²-(aq) + H,O(1) [fast]
[slow]
(a) What is the overall equation?
(b) Identify the reaction intermediate(s), if any.
(c) What are the molecularity and the rate law for each step?
(d) Is the mechanism consistent with the actual rate law:
k[CO,][OH¯]?
rate
Transcribed Image Text:16.59 A proposed mechanism for the reaction of carbon dioxide with hydroxide ion in aqueous solution is (1) СО,(ад) + ОН (аq) —> НСО, (аq) (2) HCO,-(aq) + OH¯(aq) → CO,²-(aq) + H,O(1) [fast] [slow] (a) What is the overall equation? (b) Identify the reaction intermediate(s), if any. (c) What are the molecularity and the rate law for each step? (d) Is the mechanism consistent with the actual rate law: k[CO,][OH¯]? rate
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