16. What is the reactive intermediate formed in the addition-elimination mechanism of nucleophilic aromatic substitution? A. Carbocation B. Radical C. Carbanion D. Benzyne
16. What is the reactive intermediate formed in the addition-elimination mechanism of nucleophilic aromatic substitution? A. Carbocation B. Radical C. Carbanion D. Benzyne
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Can you explain the reasons and concepts for why these answers are true?
![**Question 16: What is the reactive intermediate formed in the addition-elimination mechanism of nucleophilic aromatic substitution?**
Options:
- A. Carbocation
- B. Radical
- C. Carbanion (highlighted)
- D. Benzyne
**Explanation:**
The correct answer is option C. Carbanion. In the addition-elimination mechanism of nucleophilic aromatic substitution, a carbanion intermediate is formed. This process involves the attack of a nucleophile on an aromatic compound, leading to the formation of an anionic intermediate (carbanion) before the elimination step occurs. This intermediate is crucial for facilitating the substitution reaction on the aromatic ring.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F9955227f-949b-4b17-9185-e62a12275656%2Fb223d291-b6f3-4983-87a0-d05851cc33dc%2Fqcsifm2_processed.png&w=3840&q=75)
Transcribed Image Text:**Question 16: What is the reactive intermediate formed in the addition-elimination mechanism of nucleophilic aromatic substitution?**
Options:
- A. Carbocation
- B. Radical
- C. Carbanion (highlighted)
- D. Benzyne
**Explanation:**
The correct answer is option C. Carbanion. In the addition-elimination mechanism of nucleophilic aromatic substitution, a carbanion intermediate is formed. This process involves the attack of a nucleophile on an aromatic compound, leading to the formation of an anionic intermediate (carbanion) before the elimination step occurs. This intermediate is crucial for facilitating the substitution reaction on the aromatic ring.
![**Question 15:**
*What is the major organic product obtained from the following reaction?*
**Reaction Description:**
- Reactant: Benzene with a chlorine substituent (chlorobenzene)
- Reagents: \( \text{Cl}_2 \) and \( \text{FeCl}_3 \)
**Possible Products:**
- **I.** Para-dichlorobenzene (chlorine substituents at 1,4 positions)
- **II.** Benzyl chloride (chlorobenzene with a chloromethyl group)
- **III.** Meta-dichlorobenzene (chlorine substituents at 1,3 positions)
- **IV.** Ortho-dichlorobenzene (chlorine substituents at 1,2 positions)
**Correct Answer:**
- **D. IV** (Highlighted as the major product)
**Explanation of the Reaction:**
- The reaction involves an electrophilic aromatic substitution where chlorine is added to the benzene ring in the presence of a catalyst \( \text{FeCl}_3 \).
- Given the initial chlorine substituent, the ortho position (1,2 positions) is favored, making Product IV the major organic product.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F9955227f-949b-4b17-9185-e62a12275656%2Fb223d291-b6f3-4983-87a0-d05851cc33dc%2Fe47l94lg_processed.png&w=3840&q=75)
Transcribed Image Text:**Question 15:**
*What is the major organic product obtained from the following reaction?*
**Reaction Description:**
- Reactant: Benzene with a chlorine substituent (chlorobenzene)
- Reagents: \( \text{Cl}_2 \) and \( \text{FeCl}_3 \)
**Possible Products:**
- **I.** Para-dichlorobenzene (chlorine substituents at 1,4 positions)
- **II.** Benzyl chloride (chlorobenzene with a chloromethyl group)
- **III.** Meta-dichlorobenzene (chlorine substituents at 1,3 positions)
- **IV.** Ortho-dichlorobenzene (chlorine substituents at 1,2 positions)
**Correct Answer:**
- **D. IV** (Highlighted as the major product)
**Explanation of the Reaction:**
- The reaction involves an electrophilic aromatic substitution where chlorine is added to the benzene ring in the presence of a catalyst \( \text{FeCl}_3 \).
- Given the initial chlorine substituent, the ortho position (1,2 positions) is favored, making Product IV the major organic product.
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