16. Fill in the blanks in the reactions below 1.03 2. Me₂S 1.03 OACH 2. H₂O2 Three (3) Products 1. BH3, THF/H₂O 2. H₂O2, NaOH 1. Hg(OAc)2/H2O 2. NaBH4 HO. H
16. Fill in the blanks in the reactions below 1.03 2. Me₂S 1.03 OACH 2. H₂O2 Three (3) Products 1. BH3, THF/H₂O 2. H₂O2, NaOH 1. Hg(OAc)2/H2O 2. NaBH4 HO. H
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![## Organic Chemistry Reactions
**Exercise 16: Fill in the blanks in the reactions below**
### Reaction Details:
#### 1. Ozonolysis Reaction
- **Reactants:**
- An unknown alkene.
- **Reagents:**
- Step 1: \( \text{O}_3 \)
- Step 2: \( \text{Me}_2\text{S} \)
- **Products:**
- Two aldehydes/ketones, with one being depicted as:
- \[ \text{O}=\text{C}-\text{C}-\text{C}-\text{C}=\text{O} \]
#### 2. Ozonolysis with Oxidative Workup
- **Reactants:**
- A bicyclic alkene structure.
- **Reagents:**
- Step 1: \( \text{O}_3 \)
- Step 2: \( \text{H}_2\text{O}_2 \)
- **Products:**
- Three products are expected (actual structures not provided).
#### 3. Hydroboration-Oxidation
- **Reactants:**
- An unidentified alkene.
- **Reagents:**
- Step 1: \( \text{BH}_3, \text{THF}/\text{H}_2\text{O} \)
- Step 2: \( \text{H}_2\text{O}_2, \text{NaOH} \)
- **Product:**
- Depicted as an alcohol with two equivalent groups: \[ \text{HO}-\text{C}(-\text{CH}_3)(-\text{CH}_3) \]
#### 4. Oxymercuration-Demercuration
- **Reactants:**
- An unspecified alkene.
- **Reagents:**
- Step 1: \( \text{Hg(OAc)}_2/\text{H}_2\text{O} \)
- Step 2: \( \text{NaBH}_4 \)
- **Product:**
- An alcohol with a different structure from the hydroboration-oxidation product.
### Notes:
- These reaction mechanisms demonstrate common transformations in organic chemistry using different reagents and conditions to achieve oxidation, reduction, and](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fbefba8bf-7f0e-40cd-adc4-144bb2c0614f%2Fa23f5ec4-4d5f-4eb2-a845-9841424791bd%2Fgtypn3j_processed.jpeg&w=3840&q=75)
Transcribed Image Text:## Organic Chemistry Reactions
**Exercise 16: Fill in the blanks in the reactions below**
### Reaction Details:
#### 1. Ozonolysis Reaction
- **Reactants:**
- An unknown alkene.
- **Reagents:**
- Step 1: \( \text{O}_3 \)
- Step 2: \( \text{Me}_2\text{S} \)
- **Products:**
- Two aldehydes/ketones, with one being depicted as:
- \[ \text{O}=\text{C}-\text{C}-\text{C}-\text{C}=\text{O} \]
#### 2. Ozonolysis with Oxidative Workup
- **Reactants:**
- A bicyclic alkene structure.
- **Reagents:**
- Step 1: \( \text{O}_3 \)
- Step 2: \( \text{H}_2\text{O}_2 \)
- **Products:**
- Three products are expected (actual structures not provided).
#### 3. Hydroboration-Oxidation
- **Reactants:**
- An unidentified alkene.
- **Reagents:**
- Step 1: \( \text{BH}_3, \text{THF}/\text{H}_2\text{O} \)
- Step 2: \( \text{H}_2\text{O}_2, \text{NaOH} \)
- **Product:**
- Depicted as an alcohol with two equivalent groups: \[ \text{HO}-\text{C}(-\text{CH}_3)(-\text{CH}_3) \]
#### 4. Oxymercuration-Demercuration
- **Reactants:**
- An unspecified alkene.
- **Reagents:**
- Step 1: \( \text{Hg(OAc)}_2/\text{H}_2\text{O} \)
- Step 2: \( \text{NaBH}_4 \)
- **Product:**
- An alcohol with a different structure from the hydroboration-oxidation product.
### Notes:
- These reaction mechanisms demonstrate common transformations in organic chemistry using different reagents and conditions to achieve oxidation, reduction, and
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