Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:### Infrared (IR) Spectrum Analysis
The IR spectrum provided gives an insight into the functional groups present within a chemical compound. The x-axis represents the wavelength in wavenumbers (cm⁻¹), ranging from 4000 cm⁻¹ to 500 cm⁻¹, whereas the y-axis shows percent transmittance, ranging from 0% to 100%.
**Key Absorption Peaks:**
1. **3283 cm⁻¹**: This strong, broad absorption band is characteristic of N-H stretching vibrations, typically found in primary amines.
2. **2966 cm⁻¹**: This peak corresponds to C-H stretching vibrations, which are common in many organic compounds.
3. **2814 cm⁻¹**: This band can indicate aldehyde C-H stretching.
4. **1452 cm⁻¹ and 1379 cm⁻¹**: These peaks are often due to bending vibrations of -CH2- and -CH3 groups.
5. **1327 cm⁻¹**: This absorption can be linked to the presence of C-N stretching, common in amines.
6. **1181 cm⁻¹, 1093 cm⁻¹**: These peaks are typically associated with C-N stretching vibrations, providing further evidence of amines.
7. **1119 cm⁻¹**: Another C-N stretching band indicative of amines.
8. **1047 cm⁻¹**: This is generally a C-O stretching vibration, found in alcohols and ethers.
9. **727 cm⁻¹**: This peak can be attributed to aromatic C-H bending.
### Question Analysis
- **Question:** Is this IR spectrum consistent with the structure of an alcohol, a ketone, a carboxylic acid, a primary amine, or a secondary amine?
### Interpretation:
The presence of a strong N-H stretch around 3283 cm⁻¹ and multiple C-N stretching peaks strongly suggest that the compound is an amine. Specifically:
- The **3283 cm⁻¹** peak indicates an N-H stretch, supporting the presence of a primary amine.
- Multiple peaks between **1300 cm⁻¹ and 1200 cm⁻¹** align with C-N stretching vibrations.
Based on the IR spectrum features discussed, the analyzed compound is most consistent with the structure of a **primary amine**.
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