1500 1003 <-2965 2014 8 1130 1452 1379 727 % TRANSMITTANCE 9 3283 1327 10 1108 1047 9821

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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### Infrared (IR) Spectrum Analysis

The IR spectrum provided gives an insight into the functional groups present within a chemical compound. The x-axis represents the wavelength in wavenumbers (cm⁻¹), ranging from 4000 cm⁻¹ to 500 cm⁻¹, whereas the y-axis shows percent transmittance, ranging from 0% to 100%.

**Key Absorption Peaks:**

1. **3283 cm⁻¹**: This strong, broad absorption band is characteristic of N-H stretching vibrations, typically found in primary amines.

2. **2966 cm⁻¹**: This peak corresponds to C-H stretching vibrations, which are common in many organic compounds.

3. **2814 cm⁻¹**: This band can indicate aldehyde C-H stretching.

4. **1452 cm⁻¹ and 1379 cm⁻¹**: These peaks are often due to bending vibrations of -CH2- and -CH3 groups.

5. **1327 cm⁻¹**: This absorption can be linked to the presence of C-N stretching, common in amines.

6. **1181 cm⁻¹, 1093 cm⁻¹**: These peaks are typically associated with C-N stretching vibrations, providing further evidence of amines.

7. **1119 cm⁻¹**: Another C-N stretching band indicative of amines.

8. **1047 cm⁻¹**: This is generally a C-O stretching vibration, found in alcohols and ethers.

9. **727 cm⁻¹**: This peak can be attributed to aromatic C-H bending.

### Question Analysis
- **Question:** Is this IR spectrum consistent with the structure of an alcohol, a ketone, a carboxylic acid, a primary amine, or a secondary amine?

### Interpretation:
The presence of a strong N-H stretch around 3283 cm⁻¹ and multiple C-N stretching peaks strongly suggest that the compound is an amine. Specifically:
- The **3283 cm⁻¹** peak indicates an N-H stretch, supporting the presence of a primary amine.
- Multiple peaks between **1300 cm⁻¹ and 1200 cm⁻¹** align with C-N stretching vibrations.

Based on the IR spectrum features discussed, the analyzed compound is most consistent with the structure of a **primary amine**.
Transcribed Image Text:### Infrared (IR) Spectrum Analysis The IR spectrum provided gives an insight into the functional groups present within a chemical compound. The x-axis represents the wavelength in wavenumbers (cm⁻¹), ranging from 4000 cm⁻¹ to 500 cm⁻¹, whereas the y-axis shows percent transmittance, ranging from 0% to 100%. **Key Absorption Peaks:** 1. **3283 cm⁻¹**: This strong, broad absorption band is characteristic of N-H stretching vibrations, typically found in primary amines. 2. **2966 cm⁻¹**: This peak corresponds to C-H stretching vibrations, which are common in many organic compounds. 3. **2814 cm⁻¹**: This band can indicate aldehyde C-H stretching. 4. **1452 cm⁻¹ and 1379 cm⁻¹**: These peaks are often due to bending vibrations of -CH2- and -CH3 groups. 5. **1327 cm⁻¹**: This absorption can be linked to the presence of C-N stretching, common in amines. 6. **1181 cm⁻¹, 1093 cm⁻¹**: These peaks are typically associated with C-N stretching vibrations, providing further evidence of amines. 7. **1119 cm⁻¹**: Another C-N stretching band indicative of amines. 8. **1047 cm⁻¹**: This is generally a C-O stretching vibration, found in alcohols and ethers. 9. **727 cm⁻¹**: This peak can be attributed to aromatic C-H bending. ### Question Analysis - **Question:** Is this IR spectrum consistent with the structure of an alcohol, a ketone, a carboxylic acid, a primary amine, or a secondary amine? ### Interpretation: The presence of a strong N-H stretch around 3283 cm⁻¹ and multiple C-N stretching peaks strongly suggest that the compound is an amine. Specifically: - The **3283 cm⁻¹** peak indicates an N-H stretch, supporting the presence of a primary amine. - Multiple peaks between **1300 cm⁻¹ and 1200 cm⁻¹** align with C-N stretching vibrations. Based on the IR spectrum features discussed, the analyzed compound is most consistent with the structure of a **primary amine**.
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