15.00 pH (a) 7.08 14.50 ΔΡΜΙΔΝ 12 10 8 0 (b) 0 0.450 12 10 0 0 5 10 15 20 25 5 10 15 20 25 Volume of titrant (ml) Volume of titrant (mL) 1 mol CH3COOH=: 1mol NaOH, M11(205)=0,0998-15 M1=0073_m=0073*60_5=0.0905 14.88 Δ'ΡΜΙΔV» 30 20 10 0 -10 -20 -30 (c) 1.19 5 10 15 20 25 Volume of titrant (ml)

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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A7

15.00
PH
12
10
0
(a)
7.08
14.50
ApH/AV
12
10
8
(b)
0.450
14.88
A³pH/AV²
30
20
10
0
-10
-20
-30
0
5
(c)
10 15 20 25
Volume of titrant (mL)
0
0
5 10 15 20 25
Volume of titrant (mL)
0 5 10 15 20 25
Volume of titrant (mL)
1 mol CH3COOH= 1mol NaOH, M1 (20.5)=0.0998*15, M1-0.073, m-0.073*60.5-0.0905
1.19
Transcribed Image Text:15.00 PH 12 10 0 (a) 7.08 14.50 ApH/AV 12 10 8 (b) 0.450 14.88 A³pH/AV² 30 20 10 0 -10 -20 -30 0 5 (c) 10 15 20 25 Volume of titrant (mL) 0 0 5 10 15 20 25 Volume of titrant (mL) 0 5 10 15 20 25 Volume of titrant (mL) 1 mol CH3COOH= 1mol NaOH, M1 (20.5)=0.0998*15, M1-0.073, m-0.073*60.5-0.0905 1.19
20.5 ml of vinegar sample that contains acetic acid (CH3COOH, pKa 4.76, M.Wt.60.05
g/mol) were titrated against 0.0998 M sodium hydroxide aqueous solution. By using the
titration curve, calculate how many grams of the acid do exist in the vinegar sample?
Normal Titration
First Derivative
Second Derivative
Volume
(ml)
PH
ApH
AV
0.00
2.00
4.52
-0.273
4.00
5.06
-0.033
10.00
5.89
-0.002
12.00
6.15
0.055
14.00
0.140
15.00
7.08
1.19
pH
12
10
C
Volume
(ml)
1.00
3.00
7.00
11.00
13.00
14.50
APH/AV
12
10
(b)
ApH
AV
0815
0.270
0.138
0.130
0.240
0.450
Volume
(mt)
2.00
5.00
9.00
12.00
13.75
14 88
A'PH/AV
30
20
10
(c)
Transcribed Image Text:20.5 ml of vinegar sample that contains acetic acid (CH3COOH, pKa 4.76, M.Wt.60.05 g/mol) were titrated against 0.0998 M sodium hydroxide aqueous solution. By using the titration curve, calculate how many grams of the acid do exist in the vinegar sample? Normal Titration First Derivative Second Derivative Volume (ml) PH ApH AV 0.00 2.00 4.52 -0.273 4.00 5.06 -0.033 10.00 5.89 -0.002 12.00 6.15 0.055 14.00 0.140 15.00 7.08 1.19 pH 12 10 C Volume (ml) 1.00 3.00 7.00 11.00 13.00 14.50 APH/AV 12 10 (b) ApH AV 0815 0.270 0.138 0.130 0.240 0.450 Volume (mt) 2.00 5.00 9.00 12.00 13.75 14 88 A'PH/AV 30 20 10 (c)
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