15. Which set of parameters below all indicate a product favored reaction: AG <0; AH<0; AS > 0 AG<0; AH>0; AS> 0 a b. C. AG <0; AH<0; AS <0 d. AG>0; AH> 0; AS >O 16. How many reactive intermediates are present in the reaction in the energy diagram? a 0 b. 1 c. 2 d. 3 In 17. Oxidation in organic reactions can be recognized by a. An increase in the number of C-H and C-heteroatoms bonds b. A decrease in the number of C-H bonds and C-heteroatom bonds c. An increase in the number of C-H bonds and a decrease in the number of C-heteroatom bonds d. A decrease in the number of C-H bonds and an increase in the number of C-heteroatom bonds
15. Which set of parameters below all indicate a product favored reaction: AG <0; AH<0; AS > 0 AG<0; AH>0; AS> 0 a b. C. AG <0; AH<0; AS <0 d. AG>0; AH> 0; AS >O 16. How many reactive intermediates are present in the reaction in the energy diagram? a 0 b. 1 c. 2 d. 3 In 17. Oxidation in organic reactions can be recognized by a. An increase in the number of C-H and C-heteroatoms bonds b. A decrease in the number of C-H bonds and C-heteroatom bonds c. An increase in the number of C-H bonds and a decrease in the number of C-heteroatom bonds d. A decrease in the number of C-H bonds and an increase in the number of C-heteroatom bonds
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![15. Which set of parameters below all indicate a product-favored reaction:
a
AG <0; AH<0; AS > 0
b.
AG<0; AH>0; AS> 0
C. AG <0; AH<0; AS <0
d.
AG>0; AH> 0; AS > O
16. How many reactive intermediates are present in the reaction in the energy diagram?
a 0
b.
1
c. 2
d. 3
17. Oxidation in organic reactions can be recognized by
An increase in the number of C-H and C-heteroatoms bonds
b.
A decrease in the number of C-H bonds and C-heteroatom bonds
C.
An increase in the number of C-H bonds and a decrease in the number of C-heteroatom bonds
d. A decrease in the number of C-H bonds and an increase in the number of C-heteroatom bonds
18. Which mechanistic pathway is expected to predominate in the following reaction:
a Sul
НСЕСӨ
b.
5,2
c. E1
d. E2
19. Which mechanistic pathway is expected to predominate in the following reaction:
a. Sul
b. SN2
C. E1
d. E2
a. 1
b. 2
c. 3
d. 4°
Br
20. Classify the following carbocation structure:
a A
Br
C. C
d. D
21. Which of the following is a possible product of the reaction shown below?
H
D Br
CH₂OH
"CH₂
H₂C H
HO-
a
A and D
b.
Band C
c. A and B
d. Band D
e. All four products are expected
H₂C CHB
A
22. Which answer choice best describes the expected product of the following reaction:
H₂O
CH3
HC H
B
In
a
1. H₂SO, heat; 2. HBr
b.
1. H₂SO₂, heat; 2. BH₂; 3. H₂O₂, OH ; 4. PBr
c.
1. Kot Bu; 2. BH₂; 3. H₂O₂, OH; 4. PB₂
d.
1. POCI₂, pyridine; 2. HBr
e. 1. POCI₂, pyridine; 2. BH₂; 3. H₂O₂, OH; 4. PBr
H
-CH₂
-CH₂
x=¢¢££
CH₂
H₂SO4 A OH B
OH
23. Which reaction scheme represents the best method to achieve the indicated transformation?
300
HC
C
.x
CH₂
-H
-CH₂
X
OH
H₂C
D
CH3
D
CH₂
H
-OH](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd6496e0d-5780-4574-b21f-287f33ef6d59%2F6e59d5a2-6447-46ee-b26b-dea36d8e52c9%2F27vubol_processed.jpeg&w=3840&q=75)
Transcribed Image Text:15. Which set of parameters below all indicate a product-favored reaction:
a
AG <0; AH<0; AS > 0
b.
AG<0; AH>0; AS> 0
C. AG <0; AH<0; AS <0
d.
AG>0; AH> 0; AS > O
16. How many reactive intermediates are present in the reaction in the energy diagram?
a 0
b.
1
c. 2
d. 3
17. Oxidation in organic reactions can be recognized by
An increase in the number of C-H and C-heteroatoms bonds
b.
A decrease in the number of C-H bonds and C-heteroatom bonds
C.
An increase in the number of C-H bonds and a decrease in the number of C-heteroatom bonds
d. A decrease in the number of C-H bonds and an increase in the number of C-heteroatom bonds
18. Which mechanistic pathway is expected to predominate in the following reaction:
a Sul
НСЕСӨ
b.
5,2
c. E1
d. E2
19. Which mechanistic pathway is expected to predominate in the following reaction:
a. Sul
b. SN2
C. E1
d. E2
a. 1
b. 2
c. 3
d. 4°
Br
20. Classify the following carbocation structure:
a A
Br
C. C
d. D
21. Which of the following is a possible product of the reaction shown below?
H
D Br
CH₂OH
"CH₂
H₂C H
HO-
a
A and D
b.
Band C
c. A and B
d. Band D
e. All four products are expected
H₂C CHB
A
22. Which answer choice best describes the expected product of the following reaction:
H₂O
CH3
HC H
B
In
a
1. H₂SO, heat; 2. HBr
b.
1. H₂SO₂, heat; 2. BH₂; 3. H₂O₂, OH ; 4. PBr
c.
1. Kot Bu; 2. BH₂; 3. H₂O₂, OH; 4. PB₂
d.
1. POCI₂, pyridine; 2. HBr
e. 1. POCI₂, pyridine; 2. BH₂; 3. H₂O₂, OH; 4. PBr
H
-CH₂
-CH₂
x=¢¢££
CH₂
H₂SO4 A OH B
OH
23. Which reaction scheme represents the best method to achieve the indicated transformation?
300
HC
C
.x
CH₂
-H
-CH₂
X
OH
H₂C
D
CH3
D
CH₂
H
-OH
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