15. At 300 K, the following reaction is found to obey the rate law: Rate = k[NOCI]?: 2NOCI 2NO + CI, Consider the three postulated mechanisms given below. Then choose the response that lists all those that are possibly correct and no others. Mechanism 1 NOCI NO + CI slow CI + NOCI NOCI, fast NOCI, + NO 2NO + Cl2 fast Overall: 2NOCI 2NO + Cl, Mechanism 2 2NOCI NOCI, + NO slow NOCI, NO + Cl, fast Overall: 2NOCI 2NO + Cl2

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#6 Q15

15. At 300 K, the following reaction is found to obey the rate law: Rate = k[NOCI]?:
2NOCI = 2NO + Cl2
Consider the three postulated mechanisms given below. Then choose the response that lists all those
that are possibly correct and no others.
Mechanism 1 NOCI NO + CI
slow
CI + NOCI
NOCI,
fast
NOCI, + NO
2NO + Cl2
fast
Overall: 2NOCI 2NO + Cl,
Mechanism 2 2NOCI NOCI, + NO
slow
NOCI, A NO + Cl,
fast
Overall: 2NOCI
|2NO + Cl2
Transcribed Image Text:15. At 300 K, the following reaction is found to obey the rate law: Rate = k[NOCI]?: 2NOCI = 2NO + Cl2 Consider the three postulated mechanisms given below. Then choose the response that lists all those that are possibly correct and no others. Mechanism 1 NOCI NO + CI slow CI + NOCI NOCI, fast NOCI, + NO 2NO + Cl2 fast Overall: 2NOCI 2NO + Cl, Mechanism 2 2NOCI NOCI, + NO slow NOCI, A NO + Cl, fast Overall: 2NOCI |2NO + Cl2
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