144 13- 12. 11 Titration of Weak Acid 10- 9 86 7. Equivalence point pH, 8.72 65 A 4 3- 210 0001-0 to nojuan anta 0 5 10 15 20 25 30 35 40 45 50 Volume of 0.100 M NaOH added (mL) Fig. 10.2: Titration curve of a weak acid with a strong base The shape of a titration curve depends on the ionization constants of the acid and base and their concentrations. The example given above is for a weak acid and strong base. The equivalence point is defined as the point where the amount of base added is equal to the original amount of acid in the solution. Therefore, at the equivalence point, the number of moles of base added equals the number of moles of acid originally present in the solution being titrated. After determining the equivalence point, the concentration of the basic solution can be easily calculated with the titration formula (when the stoichiometry of acid and base is 1:1): Molarity of acid (mol/L) x Volume of acid = Molarity of base (mol/L) x Volume of base Macid X Vacid = Mbase X Vbase moles of acid in original solution = moles of base added Concentration of base (mol/L) or [base] = [moles of acid in original solution] (volume in L of base at equivalence point)

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Chapter16: Acid-base Equilibria
Section: Chapter Questions
Problem 16.149QP: A solution of weak base is titrated to the equivalence point with a strong acid. Which one of the...
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Calculate the molarity of the acetic acid solution in Fig. 10.2, when 20.0mL of that solution has been titrated with 0.100 M NaOH solution
144
13-
12.
11
Titration of Weak Acid
10-
9
86
7.
Equivalence
point pH, 8.72
65 A
4
3-
210
0001-0 to nojuan anta
0 5 10 15 20 25 30 35 40 45 50
Volume of 0.100 M NaOH added (mL)
Fig. 10.2: Titration curve of a weak acid with a strong base
The shape of a titration curve depends on the ionization constants of the acid and base and their
concentrations. The example given above is for a weak acid and strong base. The equivalence point
is defined as the point where the amount of base added is equal to the original amount of acid in the
solution. Therefore, at the equivalence point, the number of moles of base added equals the number
of moles of acid originally present in the solution being titrated. After determining the equivalence
point, the concentration of the basic solution can be easily calculated with the titration formula
(when the stoichiometry of acid and base is 1:1):
Molarity of acid (mol/L) x Volume of acid = Molarity of base (mol/L) x Volume of base
Macid X Vacid = Mbase X Vbase
moles of acid in original solution = moles of base added
Concentration of base (mol/L) or [base] =
[moles of acid in original solution]
(volume in L of base at equivalence point)
Transcribed Image Text:144 13- 12. 11 Titration of Weak Acid 10- 9 86 7. Equivalence point pH, 8.72 65 A 4 3- 210 0001-0 to nojuan anta 0 5 10 15 20 25 30 35 40 45 50 Volume of 0.100 M NaOH added (mL) Fig. 10.2: Titration curve of a weak acid with a strong base The shape of a titration curve depends on the ionization constants of the acid and base and their concentrations. The example given above is for a weak acid and strong base. The equivalence point is defined as the point where the amount of base added is equal to the original amount of acid in the solution. Therefore, at the equivalence point, the number of moles of base added equals the number of moles of acid originally present in the solution being titrated. After determining the equivalence point, the concentration of the basic solution can be easily calculated with the titration formula (when the stoichiometry of acid and base is 1:1): Molarity of acid (mol/L) x Volume of acid = Molarity of base (mol/L) x Volume of base Macid X Vacid = Mbase X Vbase moles of acid in original solution = moles of base added Concentration of base (mol/L) or [base] = [moles of acid in original solution] (volume in L of base at equivalence point)
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