14.53 Friedel-Crafts alkylation of benzene with 1-chlorobutane gave a product for which the 'H and 13С NMR spectra are shown in L Figure 14.56. The number of attached hydrogens from DEPT analysis are indicated on the 13C NMR spectrum. Assign a structure to the product. AICI3 + CH3CH2CH,CH,Cl C10H14 all CH CH3 CH2 CH3 CH C 150 100 50 Chemical shift (8, ppm) 1.7 1.6 1.5 llen 2.7 2.6 2.5 1.3 1.2 1.1 0.9 0.8 0.7 10 9. 8 7 4 3 2 1 Chemical shift (8, ppm)
14.53 Friedel-Crafts alkylation of benzene with 1-chlorobutane gave a product for which the 'H and 13С NMR spectra are shown in L Figure 14.56. The number of attached hydrogens from DEPT analysis are indicated on the 13C NMR spectrum. Assign a structure to the product. AICI3 + CH3CH2CH,CH,Cl C10H14 all CH CH3 CH2 CH3 CH C 150 100 50 Chemical shift (8, ppm) 1.7 1.6 1.5 llen 2.7 2.6 2.5 1.3 1.2 1.1 0.9 0.8 0.7 10 9. 8 7 4 3 2 1 Chemical shift (8, ppm)
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:14.53
Friedel-Crafts alkylation of benzene with 1-chlorobutane gave a product for which the 'H and 13C
NMR spectra are shown in L Figure 14.56. The number of attached hydrogens from DEPT analysis are
indicated on the 1°C NMR spectrum. Assign a structure to the product.
AIC13
+
CH3CH2CH2CH2CI
C10H14
all CH
CH3
CH2
CH3
CH
C
150
100
50
Chemical shift (8, ppm)
1.7 1.6 1.5
2.7 2.6 2.5
1.3 1.2 1.1
0.9 0.8 0.7
10
9.
8
7
6.
5
4
3
2
1
Chemical shift (8, ppm)
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