14 From the following spectral data, and using Tanabe- Sugano diagrams (Figure 11.7), calculate A for the following: 0 a. [Cr(C2O4)3]³, which has absorption bands at 23,600 and 17,400 cm 1. A third band occurs well into the ultraviolet. - b. [Ti(NCS)6]³, which has an asymmetric, slightly split band at 18,400 cm 1. (Also, suggest a reason for the splitting of this band.) c. [Ni(en)3]2+, which has three absorption bands: 11,200, 18,350, and 29,000 cm d. [VF]³, which has absorption bands at 14,800 and 23,250 cm ¹, plus a third band in the ultraviolet. Also calculate B for this ion. e. The complex VC13(CH3CN)3, which has absorption bands at 694 and 467 nm. Calculate A. and B for this complex.
14 From the following spectral data, and using Tanabe- Sugano diagrams (Figure 11.7), calculate A for the following: 0 a. [Cr(C2O4)3]³, which has absorption bands at 23,600 and 17,400 cm 1. A third band occurs well into the ultraviolet. - b. [Ti(NCS)6]³, which has an asymmetric, slightly split band at 18,400 cm 1. (Also, suggest a reason for the splitting of this band.) c. [Ni(en)3]2+, which has three absorption bands: 11,200, 18,350, and 29,000 cm d. [VF]³, which has absorption bands at 14,800 and 23,250 cm ¹, plus a third band in the ultraviolet. Also calculate B for this ion. e. The complex VC13(CH3CN)3, which has absorption bands at 694 and 467 nm. Calculate A. and B for this complex.
Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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![14 From the following spectral data, and using Tanabe-
Sugano diagrams (Figure 11.7), calculate A for the
following:
0
a. [Cr(C2O4)3]³, which has absorption bands at 23,600
and 17,400 cm 1. A third band occurs well into the
ultraviolet.
-
b. [Ti(NCS)6]³, which has an asymmetric, slightly
split band at 18,400 cm 1. (Also, suggest a reason
for the splitting of this band.)
c. [Ni(en)3]2+, which has three absorption bands:
11,200, 18,350, and 29,000 cm
d. [VF]³, which has absorption bands at 14,800 and
23,250 cm ¹, plus a third band in the ultraviolet.
Also calculate B for this ion.
e. The complex VC13(CH3CN)3, which has absorption
bands at 694 and 467 nm. Calculate A. and B for
this complex.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fe5b98de1-45af-446f-9d1e-aec0742a942d%2F5110f607-cd7d-4b3f-bee8-cdc65c5b6f58%2F3j5a9ne_processed.jpeg&w=3840&q=75)
Transcribed Image Text:14 From the following spectral data, and using Tanabe-
Sugano diagrams (Figure 11.7), calculate A for the
following:
0
a. [Cr(C2O4)3]³, which has absorption bands at 23,600
and 17,400 cm 1. A third band occurs well into the
ultraviolet.
-
b. [Ti(NCS)6]³, which has an asymmetric, slightly
split band at 18,400 cm 1. (Also, suggest a reason
for the splitting of this band.)
c. [Ni(en)3]2+, which has three absorption bands:
11,200, 18,350, and 29,000 cm
d. [VF]³, which has absorption bands at 14,800 and
23,250 cm ¹, plus a third band in the ultraviolet.
Also calculate B for this ion.
e. The complex VC13(CH3CN)3, which has absorption
bands at 694 and 467 nm. Calculate A. and B for
this complex.
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