14- 13 Titration of weak acid CH,COOH 12 Equivalence point pH, 8.72 10 Phenolphthalein [pH range Equivalence point pH, 7.00 Litmus pH range 6. Methyl orange [pH range 4 3 Titration of strong acid HCI 1 - 10 15 20 25 30 35 40 45 50 Volume of 0.100 M NaOH added (mL) Figure 14.23 The graph shows a titration curve for the titration of 25.00 mL of 0.100 M CH3CO,H (weak acid) with 0.100 M NaOH (strong base) and the titration curve for the titration of HCI (strong acid) with NaOH (strong base). The pH ranges for the color change of phenolphthalein, litmus, and methyl orange are indicated by the shaded areas. 11 Hd

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The titration curve as shown is for the titration of 25.00 mL of 0.100 M CH3CO2H with 0.100 M NaOH. The reaction can be represented as:
                           CH3 CO2 H + OH ⟶ CH3 CO2 + H2 O
(a) What is the initial pH before any amount of the NaOH solution has been added? Ka = 1.8 × 10−5 for CH3CO2H.

(b) Find the pH after 25.00 mL of the NaOH solution have been added.
(c) Find the pH after 12.50 mL of the NaOH solution has been added.
(d) Find the pH after 37.50 mL of the NaOH solution has been added.

14-
13
Titration of weak acid CH,COOH
12
Equivalence
point pH, 8.72
10
Phenolphthalein
[pH range
Equivalence
point pH, 7.00
Litmus pH range
6.
Methyl orange
[pH range
4
3
Titration of strong acid HCI
1 -
10
15
20
25
30
35
40
45
50
Volume of 0.100 M NaOH added (mL)
Figure 14.23 The graph shows a titration curve for the titration of 25.00 mL of 0.100 M CH3CO,H (weak acid) with
0.100 M NaOH (strong base) and the titration curve for the titration of HCI (strong acid) with NaOH (strong base). The
pH ranges for the color change of phenolphthalein, litmus, and methyl orange are indicated by the shaded areas.
11
Hd
Transcribed Image Text:14- 13 Titration of weak acid CH,COOH 12 Equivalence point pH, 8.72 10 Phenolphthalein [pH range Equivalence point pH, 7.00 Litmus pH range 6. Methyl orange [pH range 4 3 Titration of strong acid HCI 1 - 10 15 20 25 30 35 40 45 50 Volume of 0.100 M NaOH added (mL) Figure 14.23 The graph shows a titration curve for the titration of 25.00 mL of 0.100 M CH3CO,H (weak acid) with 0.100 M NaOH (strong base) and the titration curve for the titration of HCI (strong acid) with NaOH (strong base). The pH ranges for the color change of phenolphthalein, litmus, and methyl orange are indicated by the shaded areas. 11 Hd
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