14 12 FI: 60.201 EX: cleft\HI\ZG.ppg broad OH peak 11.225 H NMR of 3-carboxy-umbelliferone product IC FG 8.690 7.815 7.692 HO 6.920 6.767 10 8 6 2 PPM - USER: · DATE: 04/18/24 (15:51) SWI: 3994 PW: 2.4 us PD: 3.5 sec OFI:-355.2 INA: 5 PTSId: 4096 LB: 0.0 DMSO - ignore HO 2.539 -0.000 -0.053

Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter18: Carboxylic Acids
Section: Chapter Questions
Problem 18.54P
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Analyze the H1-NMR of 3-Carboxy-Umbelliferone. Assign the protons in this structure to peaks seen in the spectra. Make a table for all peaks (with observed splitting pattern and integration) for each set of Hydrogens?

14
12
FI: 60.201
EX: cleft\HI\ZG.ppg
broad OH peak
11.225
H NMR of 3-carboxy-umbelliferone product
IC FG
8.690
7.815
7.692
HO
6.920
6.767
10
8
6
2
PPM
-
USER: · DATE: 04/18/24 (15:51)
SWI: 3994
PW: 2.4 us
PD: 3.5 sec
OFI:-355.2
INA: 5
PTSId: 4096
LB: 0.0
DMSO - ignore
HO
2.539
-0.000
-0.053
Transcribed Image Text:14 12 FI: 60.201 EX: cleft\HI\ZG.ppg broad OH peak 11.225 H NMR of 3-carboxy-umbelliferone product IC FG 8.690 7.815 7.692 HO 6.920 6.767 10 8 6 2 PPM - USER: · DATE: 04/18/24 (15:51) SWI: 3994 PW: 2.4 us PD: 3.5 sec OFI:-355.2 INA: 5 PTSId: 4096 LB: 0.0 DMSO - ignore HO 2.539 -0.000 -0.053
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