**Transcription for Educational Use:****e.** Name the major product(s) of this reaction only. 1,2,2-trimethylcyclopentan-1-ol is heated in aqueous sulfuric acid.**f.** (3S, 4S)-4-methyl-3-hexanol is heated in aqueous sulfuric acid.**Explanation of Reactions:**- For part **e**, the reaction involves 1,2,2-trimethylcyclopentan-1-ol in the presence of aqueous sulfuric acid, which typically leads to dehydration reactions that form alkenes. Sulfuric acid acts as a catalyst promoting the loss of a water molecule from the alcohol to produce an alkene – in this case, the major product is likely to be a more stable alkene configuration.- For part **f**, (3S, 4S)-4-methyl-3-hexanol undergoes a similar dehydration process when heated with aqueous sulfuric acid. The stereochemistry indicated by (3S, 4S) suggests a specific 3D arrangement of the molecules, which can influence the type of alkene formed as the major product, often favoring formations that lead to greater stability and possible rearrangements.These reactions are representative of typical elimination reactions in organic chemistry, which are crucial in understanding the formation of alkenes from alcohols. 1. For the following elimination reactions (i) Write bond-line structure of the substrate and the reagent (ii) Write full mechanism for the reaction (transition state for E2, intermediate for E1) and name the reaction either as E1 or E2; (iii) Write all possible products of the reaction defining which one/s is/are major and which one/s is/are minor; (iv) Name products of the reaction if requested.

Give reactions are dehydration reactions.

Answered: 1,2,2-trimethylcyclopentan-1-ol is…

1,2,2-trimethylcyclopentan-1-ol is heated in aqueous sulfuric acid f. (3S, 4S)-4-methyl-3-hexanol is heated in aqueous sulfuric acid

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

Please don't provide handwritten solution...
Write the open structures of the molecules named below according to the IUPAC naming system 4-(tert-butyl)-5-ethilon (2E, 4Z, 6E) -4,5-diethyl-3-methyl-2,4,5-octatriene cis-3,7-diethyl-4-nonene 2-hydroxy-3-pentenal N-ethyl-N-methylpropanamine
Draw the organic products formed when allylic alcohol A is treated with each reagent.a.H2 + Pd-C b.mCPBA c. PCC d.CrO3, H2SO4, H2O e.(CH3)3COOH, Ti[OCH(CH3)2]4, (+)-DET f. (CH3)3COOH, Ti[OCH(CH3)2]4, (−)-DET g. [1] PBr3; [2] LiAlH4; [3] H2O h.HCrO4−–Amberlyst A-26 resin
Draw the structure of each isomer.
PQ-4. Predict the major product(s). (A) I Br (B) II Nal acetone Q I (C) III II (D) I and II III
Give detailed Solution with explanation
6. Write the IUPAC name for the following compounds. Show the stereochemistry whenever required (a) HO NH2 CI (b) NH2 QH но (c) он Br H. (d) (e) OH Br Br
The stereochemistry of the products of reduction depends on the reagent used, with this in mind, how would you convert 3,3-dimethylbutan-2-one [CH3COC(CH3)3] to: (a) racemic 3,3-dimethylbutan-2-ol [CH3CH(OH)C(CH3)3]; (b) only (R)-3,3- dimethylbutan-2-ol; (c) only (S)-3,3-dimethylbutan-2-ol?
2. Sketch the proper structure (including stereochemistry) for each compound. a. (4R)-3,4-diethyl-4-methylheptane b. (5S, 7R)-7-chloro-2,4,4,5,7-pentamethyldecane C. (65, 75)-3,7-dibromo-3-ethyl-6-methylnonane
This is not A or C. The second one is not A or D
There are three compounds with same molecular formula C8H9Br, andit has been known that all these three compounds contain a phenyl ring, anethyl group, and a bromide atom. A cannot react with AgNO3. B reactswith AgNO3 smoothly at room temperature. C can react with AgNO3 athigh temperature. Try to give the structures of A, B and C.
F75.