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- 12.92 Give the IUPAC name for each of the following thiols. a. CH,CHCH, SH SH b. -SH c. CH,CHCH,CH,CH, SH d. CH;CH,CH,CH,CH,CH,CH,SH(a) Give the IUPAC name for A and B. (b) Draw the product formed when A or B is treated with each reagent: [1] NaBH4, CH3OH; [2] CH3MgBr, then H2O; [3] Ph3P = CHOCH3; [4] CH3CH2CH2NH2, mild acid; [5] HOCH2CH2CH2OH, H+.#544 of Isomers (chiral) Which of the following 2-chloro-1-butanol (A), 3-chloro-1-butanol (B), and 4-chloro-1-butanol (C), contain a stereogenic carbon atom. Select one: a. A only O b. B only O c. C only O d. A and B e. A, B and C
- Draw the structure of a compound tting each description:a. an aldehyde with molecular formula C4H8Ob. a ketone with molecular formula C4H8Oc. a carboxylic acid with molecular formula C4H8O2d. an ester with molecular formula C4H8O24. Draw the line structure for the ester that can be formed from the reaction of the acid anhydride and the alcohol given below. (3) :0: :0: НО CH3-CH2- C-CH2-CH3 acid anhydride alcoholPhenylethanol can be oxidised to phenylethanal or phenylethanoic acid, depending on the reagents used (both the alcohol and the aldehyde are of interest for their antimicrobial properties, while the acid is used to treat type II hyperammonemia): A (a) (b) (c) CoH,CH,CHO phenylethanal B C6H5CH₂CH₂OHC₂H₂CH₂CO₂H phenylethanol Suggest reagents (shown as A and B in the scheme above) that could be used to carry out the oxidation of the alcohol to the aldehyde and the acid, respectively. C6H5CH₂- Suggest two other syntheses of phenylethanoic acid, in each case indicating the starting materials and other reagents required, but not giving details of mechanism. One of your proposed syntheses must start with a compound which only contains seven carbon atoms (the acid product contains eight carbon atoms). phenylethanoic acid Phenylethanal can be converted to a hydrate in the presence of aqueous acid, though the position of equilibrium is very far to the left: H H+/H₂O OH C6H5CH₂-C-H OH Explain why…
