12.26. Define the overall per-particle volumes and enthalpies of a mixture as v V/N and h H/N with N N Prove the following two relations governing their temperature and pressure dependence: dP xidVi т, (х} аT + дР дт P,x дh аT + ӘР дh dP xidHi т, (х} от P, x

Introduction to Chemical Engineering Thermodynamics
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ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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This problem is (12.26) from a book  "Thermodynamics and Statistical Mechanics An Integrated Approach by M. Scott Shell"

12.26. Define the overall per-particle volumes and enthalpies of a mixture as v V/N
and h H/N with N N Prove the following two relations governing their
temperature and pressure dependence:
dP xidVi
т, (х}
аT +
дР
дт
P,x
дh
аT +
ӘР
дh
dP xidHi
т, (х}
от
P, x
Transcribed Image Text:12.26. Define the overall per-particle volumes and enthalpies of a mixture as v V/N and h H/N with N N Prove the following two relations governing their temperature and pressure dependence: dP xidVi т, (х} аT + дР дт P,x дh аT + ӘР дh dP xidHi т, (х} от P, x
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