11. The reaction 2NO + O2 → 2NO2 obeys the experimentally determined rate law: Rate = k[NO]°[O2]. Which of the following mechanisms is consistent with the experimental rate law? NO + NO → N2O2 N2O2 + O2 → 2NO2 A) (slow) (fast) B) NO + O2→ NO3 (fast) (slow) NO3 + NO → 2NO2 C) 2NO → N,O2 (fast) (slow) (fast) N2O2 → NO2 + O NO +0 → NO2 O2 + NO → NO2 + O O + NO → NO2 (slow) (fast) D) E) None of these are valid mechanisms

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11. The reaction 2NO + O2 → 2NO2 obeys the experimentally determined rate law: Rate = k[NO]°[O2]. Which of
the following mechanisms is consistent with the experimental rate law?
NO + NO → N2O2
N2O2 + O2 → 2NO2
A)
(slow)
(fast)
B)
NO + O2→ NO3
(fast)
(slow)
NO3 + NO → 2NO2
C)
2NO → N,O2
(fast)
(slow)
(fast)
N2O2 → NO2 + O
NO +0 → NO2
O2 + NO → NO2 + O
O + NO → NO2
(slow)
(fast)
D)
E)
None of these are valid mechanisms
Transcribed Image Text:11. The reaction 2NO + O2 → 2NO2 obeys the experimentally determined rate law: Rate = k[NO]°[O2]. Which of the following mechanisms is consistent with the experimental rate law? NO + NO → N2O2 N2O2 + O2 → 2NO2 A) (slow) (fast) B) NO + O2→ NO3 (fast) (slow) NO3 + NO → 2NO2 C) 2NO → N,O2 (fast) (slow) (fast) N2O2 → NO2 + O NO +0 → NO2 O2 + NO → NO2 + O O + NO → NO2 (slow) (fast) D) E) None of these are valid mechanisms
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