11. An unknown sample is being submitted for elemental analysis. The follow- ing results are obtained: 72.4 % C, 13.8 % H and 0 % N. Knowing that the sample's molecular weight is 116, what is the molecular formula of this com- pound? Propose a structure.

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Chapter1: Chemical Foundations
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11,12,13
poihts.
Calculate the standard refractive index.
11. An unknown sample is being submitted for elemental analysis. The follow-
ing results are obtained: 72.4 % C, 13.8 % H and 0 % N. Knowing that the
sample's molecular weight is 116, what is the molecular formula of this com-
pound? Propose a structure.
melting
119
e up) be-
ts.
12. You have two samples: one is known to be acetophenone, while the other one
is 1-phenylethanol. How would you know which one is which using infrared
spectroscopy?
HO,
13. Luis A. reacted cyclohexene with H, in the presence of a Pd catalyst. How
could Luis follow the reaction using IR?
Boiling
point
14. Esterification of acetic acid with isopentanol in acidic conditions led to a
liquid. Two carbonyl peaks are observed in IR: a large peak at 1730 cm-1, with
a smaller peak at 1715 cm-1. Explain.
15. How would you decide which compound is which using only IR spectroscopy?
Benzoic acid and acetophenone
b. Ethyl methyl ether and propanol
. Acetophenone and benzaldehyde
d. 2-Cyanobutane and 2-methylbutanoic acid
Phenol and cyclohexanol
a.
e.
elemental analysis. The IR spectrum of her sample shows peaks at 3028, 1710
(strong), 1600 (sharp), and 1377 cm-1.
16. Z. a with as shown by
Transcribed Image Text:poihts. Calculate the standard refractive index. 11. An unknown sample is being submitted for elemental analysis. The follow- ing results are obtained: 72.4 % C, 13.8 % H and 0 % N. Knowing that the sample's molecular weight is 116, what is the molecular formula of this com- pound? Propose a structure. melting 119 e up) be- ts. 12. You have two samples: one is known to be acetophenone, while the other one is 1-phenylethanol. How would you know which one is which using infrared spectroscopy? HO, 13. Luis A. reacted cyclohexene with H, in the presence of a Pd catalyst. How could Luis follow the reaction using IR? Boiling point 14. Esterification of acetic acid with isopentanol in acidic conditions led to a liquid. Two carbonyl peaks are observed in IR: a large peak at 1730 cm-1, with a smaller peak at 1715 cm-1. Explain. 15. How would you decide which compound is which using only IR spectroscopy? Benzoic acid and acetophenone b. Ethyl methyl ether and propanol . Acetophenone and benzaldehyde d. 2-Cyanobutane and 2-methylbutanoic acid Phenol and cyclohexanol a. e. elemental analysis. The IR spectrum of her sample shows peaks at 3028, 1710 (strong), 1600 (sharp), and 1377 cm-1. 16. Z. a with as shown by
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