11. 2 A+B OC+ D The following results were obtained when the reaction represented above was studied at 25°C. Initial, [B]. Experiment # Initial, [A]. Initial Rate of Formation of C (mol L-' min') 1 0.25 0.75 4.3 x 104 2 0.75 0.75 1.3 x 103 3 1.50 1.50 5.3 x 103 4 1.75 8.0 x 103 (a) Determine the order of the reaction with respect to A and to B. Justify your answer. (trickier logic here, I think) (b) Write the rate law for the reaction: (c) Calculate the value of the rate constant, specifying units. (d) Determine the initial rate of change of [A] in Experiment 3. (note that the initial rates are with respect to [C]) (e) Identify which of the reaction mechanisms represented below is consistent with the rate law developed in part (b). Justify your choice. 1. A+B OC+M Fast Justify M+A OD Slow 2. B2M Fast equilibrium M+AD C+X Slow
11. 2 A+B OC+ D The following results were obtained when the reaction represented above was studied at 25°C. Initial, [B]. Experiment # Initial, [A]. Initial Rate of Formation of C (mol L-' min') 1 0.25 0.75 4.3 x 104 2 0.75 0.75 1.3 x 103 3 1.50 1.50 5.3 x 103 4 1.75 8.0 x 103 (a) Determine the order of the reaction with respect to A and to B. Justify your answer. (trickier logic here, I think) (b) Write the rate law for the reaction: (c) Calculate the value of the rate constant, specifying units. (d) Determine the initial rate of change of [A] in Experiment 3. (note that the initial rates are with respect to [C]) (e) Identify which of the reaction mechanisms represented below is consistent with the rate law developed in part (b). Justify your choice. 1. A+B OC+M Fast Justify M+A OD Slow 2. B2M Fast equilibrium M+AD C+X Slow
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
Can you please help me with this?
![11.
2 A+ ВОС+D
The following results were obtained when the reaction represented above was studied at 25°C.
Experiment #
Initial, [A].
Initial, [B].
Initial Rate of Formation of C
(mol L·' min')
1
0.25
0.75
4.3 x 104
0.75
0.75
1.3 x 103
3
1.50
1.50
5.3 x 103
4
1.75
?
8.0 x 103
(a) Determine the order of the reaction with respect to A and to B. Justify your answer. (trickier logic here, I think)
(b)
Write the rate law for the reaction:
(c)
Calculate the value of the rate constant, specifying units.
(d)
Determine the initial rate of change of [A] in Experiment 3. (note that the initial rates are with respect to [C])
(e)
Identify which of the reaction mechanisms represented below is consistent with the rate law developed in
part (b). Justify your choice.
A+B OC+ M
1.
Fast
Justify
M+A OD
Slow
2.
Fast equilibrium
Slow
B2M
M +A OC+ X
A+X OD
Fast
Fast equilibrium
Slow
3.
A+B2M
M+A OC+X
Fast
ХOD
(f) For experiment 2, calculate the concentration of B remaining when exactly one-half of the original amount of A
had been consumed.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F310fa1be-a638-47b3-9316-1b971054d314%2F58718667-cd1b-4b0e-bf29-a234cade786b%2Fuvdgeas_processed.jpeg&w=3840&q=75)
Transcribed Image Text:11.
2 A+ ВОС+D
The following results were obtained when the reaction represented above was studied at 25°C.
Experiment #
Initial, [A].
Initial, [B].
Initial Rate of Formation of C
(mol L·' min')
1
0.25
0.75
4.3 x 104
0.75
0.75
1.3 x 103
3
1.50
1.50
5.3 x 103
4
1.75
?
8.0 x 103
(a) Determine the order of the reaction with respect to A and to B. Justify your answer. (trickier logic here, I think)
(b)
Write the rate law for the reaction:
(c)
Calculate the value of the rate constant, specifying units.
(d)
Determine the initial rate of change of [A] in Experiment 3. (note that the initial rates are with respect to [C])
(e)
Identify which of the reaction mechanisms represented below is consistent with the rate law developed in
part (b). Justify your choice.
A+B OC+ M
1.
Fast
Justify
M+A OD
Slow
2.
Fast equilibrium
Slow
B2M
M +A OC+ X
A+X OD
Fast
Fast equilibrium
Slow
3.
A+B2M
M+A OC+X
Fast
ХOD
(f) For experiment 2, calculate the concentration of B remaining when exactly one-half of the original amount of A
had been consumed.
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 4 steps with 3 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY