10. Which of the following is a reducing sugar? with explanation CH₂OH A B CH2OH CH3 OH OH بسمة CH2OH OH OH OH OH HO. C HOH2C OH HOH2C OH HO OH HO D CH₂OH OH OH E All the above
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- please give clear answersa) Which of the following monosaccharides will react with Tollens' reagent? Circle all that аpply. СООН CH2OH CH2OH OCH3 но- H- ОН HO FH OH CH2OH CH2OH OH II III IV V b) Decide whether the disaccharide shown below is a reducing or non-reducing sugar CH2OH но Но- ОН CH2 но Но OH OH 우 오Click on the glycosidic linkage НО CH2OH ОН ОН CH₂OH ОН ОН ОН
- Give clear explanation answerrivatives: Nucleophilic Acyl Substitution Reactions - EOC O C-O [References] One step in the gluconeogenesis pathway for the biosynthesis of glucose is the partial reduction of 3-phosphoglycerate to give glyceraldehyde 3-phosphate. The process occurs by phosphorylation with ATP to give 1,3-bisphosphoglycerate, reaction with a thiol group on the enzyme to give an enzyme-bound thioester, and reduction with NADH. H-C-OH ATP ADP CH₂OPO32- 3-phosphoglycerate 0= OPO32- C H-C-OH CH₂OPO32 1,3-bisphosphoglycerate Enz-SH PO43- O= C S-Enz H-C-OH CH₂OPO3² (Enzyme-bound thioester) NADH/H+ O=C NAD*, Enz-SH H H-C-OH CH₂OPO3²- glyceraldehyde 3-phosphate Propose a structure for the first intermediate in the reaction of the enzyme-bound thioester with NADH to form glyceraldehyde 3-phosphate. To simplify the drawing process, substitute the structure below for the enzyme-bound thioester. S-CH3 substitute for the CH2CH3 enzyme-bound thioester You do not have to consider stereochemistry. • You do not have…Draw the organic products formed in attached reaction, and indicate the stereochemistry of products that contain stereogenic centers.