10. According to the background information the Group III reagent is to be buffered at pH 10 to proouce a nign enough (OH) to precipitate the Group II ions, but not high enough to precipitate the group IV ions. a. If a solution contained Fe ions at a concentration of 0.1 M, what pH would have to be reached to precipitate 99% of the Fe" as Fe(OH)»? Hint: Determine (Fe") after precipitation and use it and the Kep to determine (OH) If a solution contained NP ions at a concentration of 0.1 M, what pH would have to be reached to cipitate 99% of the Ni? as Ni(OH)2?

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the ksp for the Fe(OH)3 is 4.0x10^-38
10. According to the background information the Group III reagent is to be buffered at pH 10 to procuce a nign
enough (OH- to precipitate the Group III ions, but not high enough to precipitate the group IV ions.
a. If a solution contained Fe" ions at a concentration of 0.1 M, what pH would have to be reached to
precipitate 99% of the Fe" as Fe(OH)s? Hint: Determine (Fe") after precipitation and use it and the Keo to
determine (OH
b. If a solution contained Ni* ions at a concentration of 0.1 M, what pH would have to be reached to
precipitate 99% of the Ni as Ni(OH)2?
c. Based on your answers to a. and b., if enough OH- was added to reach a pH of 10, would the Fe3 be
selectively precipitated, leaving the Ni2 in solution? Explain?
No
Transcribed Image Text:the ksp for the Fe(OH)3 is 4.0x10^-38 10. According to the background information the Group III reagent is to be buffered at pH 10 to procuce a nign enough (OH- to precipitate the Group III ions, but not high enough to precipitate the group IV ions. a. If a solution contained Fe" ions at a concentration of 0.1 M, what pH would have to be reached to precipitate 99% of the Fe" as Fe(OH)s? Hint: Determine (Fe") after precipitation and use it and the Keo to determine (OH b. If a solution contained Ni* ions at a concentration of 0.1 M, what pH would have to be reached to precipitate 99% of the Ni as Ni(OH)2? c. Based on your answers to a. and b., if enough OH- was added to reach a pH of 10, would the Fe3 be selectively precipitated, leaving the Ni2 in solution? Explain? No
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