(10) i) Use the quantum mechanical kinetic energy operator T, to find the kinetic energy of the first 2m dx? excited state of the Particle in a Box (with n = 2). ii) Then, use the relationship of kinetic energy and momentum (KE =p²/2m) to find an equation for the de Broglie wavelength of the particle in a one-dimensional box as a function only of the box length L and quantum number n. iii) Sketch the wavefunction in the box to verify that the expression you obtained in part ii) is correct.

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(10) i) Use the quantum mechanical kinetic energy operator T, =
to find the kinetic energy of the first
2m dx?
excited state of the Particle in a Box (with n = 2). ii) Then, use the relationship of kinetic energy and momentum (KE
= p?/2m) to find an equation for the de Broglie wavelength of the particle in a one-dimensional box as a function only
of the box length L and quantum number n. iii) Sketch the wavefunction in the box to verify that the expression you
obtained in part ii) is correct.
Transcribed Image Text:(10) i) Use the quantum mechanical kinetic energy operator T, = to find the kinetic energy of the first 2m dx? excited state of the Particle in a Box (with n = 2). ii) Then, use the relationship of kinetic energy and momentum (KE = p?/2m) to find an equation for the de Broglie wavelength of the particle in a one-dimensional box as a function only of the box length L and quantum number n. iii) Sketch the wavefunction in the box to verify that the expression you obtained in part ii) is correct.
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