(1.)T-butyl bromide is converted into t-butyl alcohol in a solvent containing 90 percent acetone and 10 percent water. The first order reaction is given by (CH3)3CBr+H₂O-(CH3)3COH+HBr The following table gives the data for the concentration of t-butyl bromide versus time obtained from the batch reactor with fixed volume.

Introduction to Chemical Engineering Thermodynamics
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Chapter1: Introduction
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Using differential method. Hand-written

(1.)T-buty
butyl bromide is converted into t-butyl
alcohol in a solvent containing 90 percent
acetone and 10 percent water. The first order
reaction is given by
(CH3)3CBr+H₂O-(CH3)3COH+HBr
The following table gives the data for the
concentration of t-butyl bromide versus time
obtained from the batch reactor with fixed
volume.
t(min)
(CH3)3CBr
0.1056
0
9
0.0961
18
0.0856
27
0.0767
40
0.0645
57
0.0536
72
0.0432
105
0.0270
What is the order of the reaction? What is the rate constant of the reaction? What is the half-life of the
reaction?
Transcribed Image Text:(1.)T-buty butyl bromide is converted into t-butyl alcohol in a solvent containing 90 percent acetone and 10 percent water. The first order reaction is given by (CH3)3CBr+H₂O-(CH3)3COH+HBr The following table gives the data for the concentration of t-butyl bromide versus time obtained from the batch reactor with fixed volume. t(min) (CH3)3CBr 0.1056 0 9 0.0961 18 0.0856 27 0.0767 40 0.0645 57 0.0536 72 0.0432 105 0.0270 What is the order of the reaction? What is the rate constant of the reaction? What is the half-life of the reaction?
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