1.44. The van der Waals constant b can be used to estimate molecular sizes, assuming the molecules are shaped like spheres: 1. Convert b to units of m³/mol, using the fact that 1 m³ = 1000 L. 2. Divide by Avogadro's number to get the individual molecular contribution to b. 3. Use V = 4/3 Tr³ to estimate the radius of the molecule. Using these steps, estimate the sizes of (a) He (b) H₂O (c) C₂H₂.
1.44. The van der Waals constant b can be used to estimate molecular sizes, assuming the molecules are shaped like spheres: 1. Convert b to units of m³/mol, using the fact that 1 m³ = 1000 L. 2. Divide by Avogadro's number to get the individual molecular contribution to b. 3. Use V = 4/3 Tr³ to estimate the radius of the molecule. Using these steps, estimate the sizes of (a) He (b) H₂O (c) C₂H₂.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:1.44. The van der Waals constant b can be used to estimate
molecular sizes, assuming the molecules are shaped like
spheres: 1. Convert b to units of m³/mol, using the fact that
1 m³ = 1000 L. 2. Divide by Avogadro's number to get the
individual molecular contribution to b. 3. Use V = 4/3 πr³
to estimate the radius of the molecule. Using these steps,
estimate the sizes of (a) He (b) H₂O (c) C₂H6-
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