Azeotrope of chloroform–methanol.Vapor–liquid equilibrium data at 101.3 kPa are given for the chloroform–methanol system on p. 13-11 of Perry’s Chemical Engineers’Handbook, 6th ed. From these data, prepare plots like Figures 4.6b and 4.6c. From the plots, determine the azeotropic composition,type of azeotrope, and temperature at 101.3 kPa. 1.00.9Equilibrium line0.80.70.60.5E0.4 F0.30.2Reference line, y, = 110.1 H0.20.40.60.81.0Mole fraction isopropyl etherin liquid phase, x1(b)Mole fraction isopropyl etherin vapor phase, y1 10090VaporDew-point line80Vapor + liquid70Bubble-point line60Liquid500.20.40.60.81.0Mole fraction isopropyl ether(c)Temperature, °C

Let Component A is Methanol and Component B is Chloroform.

Answered: 1.0 0.9 Equilibrium line 0.8 0.7 0.6…

Introduction to Chemical Engineering Thermodynamics

8th Edition

ISBN:9781259696527

Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Chapter1: Introduction

Section: Chapter Questions

Problem 1.1P

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Azeotrope of chloroform–methanol.
Vapor–liquid equilibrium data at 101.3 kPa are given for the chloroform–methanol system on p. 13-11 of Perry’s Chemical Engineers’Handbook, 6th ed. From these data, prepare plots like Figures 4.6b and 4.6c. From the plots, determine the azeotropic composition,type of azeotrope, and temperature at 101.3 kPa.

1.0
0.9
Equilibrium line
0.8
0.7
0.6
0.5E
0.4 F
0.3
0.2
Reference line, y, = 11
0.1 H
0.2
0.4
0.6
0.8
1.0
Mole fraction isopropyl ether
in liquid phase, x1
(b)
Mole fraction isopropyl ether
in vapor phase, y1

100
90
Vapor
Dew-point line
80
Vapor + liquid
70
Bubble-point line
60
Liquid
50
0.2
0.4
0.6
0.8
1.0
Mole fraction isopropyl ether
(c)
Temperature, °C

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