Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question

Transcribed Image Text:1.
Write the balanced equation for the production of the brown nitrogen dioxide (NO2) gas from nitrogen and oxygen gases.
Calculate the enthalpy of the reactions given below.
N2 (g) +O2 2NO (g)
2NO (g)
AH = 180 kJ
ne
2NO(g) +Q2 (g)
AH = 112 kJ
2. Methylhydrazine (N2H3CH3) is common liquid propellant used in rocket fuels. Look for the standard molar enthalpies of
formation of the reactants and products. Calculate the AH° for the reaction per mole of N2H3CH3.
4N2H3CH3 (1) + 5N2O4 ()
12H20 (g) +9N2 (g) +4CO2 (g)
![SAMPLE PROBLEMS:
rimsts
1. Using the standard molar enthalpies of formation given, calculate the standard enthalpy of reaction for the combustion of
propane (C3He) into carbon dloxide and water.
C3HB (g) + 502 (g)
+3CO2 (g) + 4H20 (g)
CaHa (g)
-104.0
CO2 (g)
-393.5
H20 (g)
-241.8
O2 (g)
Substance
AH°: (kJ/mol)
Solution:
CM EAH°nm = [3AH°r (CO2, g) +4AH°, (H20, g)]-[AH°: (C3Ha, g) +5AH°; (O2, g)]
=[3(-393,5 kJ) +(-241.8 kJ)] – [(-104.0 kJ) + 5 () = -2043.7 kJ
2. The thermochemical equation for the incomplete combustion of carbon into carbon monoxide is represented as
20 (s) +O2 (9)
→ 200 (g)
Compute for the AH of the reaction if the overall process above can occur in two steps whose themochemical equations are
given below:
(1) C (s) +O2 (g)
(2) 2CO (g) +O2 (9)
CO2 (g)
2C02 (g)
AH = -393.5 kJ
AH = -566.0kJ](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fa3f18da7-e6f8-4405-9688-49449fb3324b%2Fe2fe6db0-d73c-44fa-8cf4-986e2be2b3c8%2Fdwkvrmx_processed.jpeg&w=3840&q=75)
Transcribed Image Text:SAMPLE PROBLEMS:
rimsts
1. Using the standard molar enthalpies of formation given, calculate the standard enthalpy of reaction for the combustion of
propane (C3He) into carbon dloxide and water.
C3HB (g) + 502 (g)
+3CO2 (g) + 4H20 (g)
CaHa (g)
-104.0
CO2 (g)
-393.5
H20 (g)
-241.8
O2 (g)
Substance
AH°: (kJ/mol)
Solution:
CM EAH°nm = [3AH°r (CO2, g) +4AH°, (H20, g)]-[AH°: (C3Ha, g) +5AH°; (O2, g)]
=[3(-393,5 kJ) +(-241.8 kJ)] – [(-104.0 kJ) + 5 () = -2043.7 kJ
2. The thermochemical equation for the incomplete combustion of carbon into carbon monoxide is represented as
20 (s) +O2 (9)
→ 200 (g)
Compute for the AH of the reaction if the overall process above can occur in two steps whose themochemical equations are
given below:
(1) C (s) +O2 (g)
(2) 2CO (g) +O2 (9)
CO2 (g)
2C02 (g)
AH = -393.5 kJ
AH = -566.0kJ
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