Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Question 1:**
Which of the following solvents is the least appropriate for an Sₙ2 reaction? (Choose the letter of your answer that corresponds to the slowest rate.)
**Solvent Structures:**
- (a) **Structure:** A line-angle drawing with three methyl groups connected to a central carbon (tert-butyl).
- (b) **Structure:** A line-angle drawing representing N,N-dimethylformamide (DMF), with a carbonyl group (C=O) attached to a nitrogen with two methyl groups.
- (c) **Structure:** A line-angle drawing of acetone, with a carbonyl group (C=O) bonded to two methyl groups.
- (d) **Structure:** A line-angle drawing representing dimethyl sulfoxide (DMSO), with a sulfur atom bonded to an oxygen (S=O) and two methyl groups.
- (e) **Structure:** A line-angle drawing of propan-1-ol, with a hydroxyl group (-OH) attached to a three-carbon linear chain.
**Explanation:**
Choose the solvent that would result in the slowest rate for an Sₙ2 reaction, focusing on factors such as polarity and proticity.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fb38afea1-bdd6-4163-a1d3-027b743d70fc%2F3cb42edd-83e1-4084-99b6-132858d15d45%2F0mv6gba_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Question 1:**
Which of the following solvents is the least appropriate for an Sₙ2 reaction? (Choose the letter of your answer that corresponds to the slowest rate.)
**Solvent Structures:**
- (a) **Structure:** A line-angle drawing with three methyl groups connected to a central carbon (tert-butyl).
- (b) **Structure:** A line-angle drawing representing N,N-dimethylformamide (DMF), with a carbonyl group (C=O) attached to a nitrogen with two methyl groups.
- (c) **Structure:** A line-angle drawing of acetone, with a carbonyl group (C=O) bonded to two methyl groups.
- (d) **Structure:** A line-angle drawing representing dimethyl sulfoxide (DMSO), with a sulfur atom bonded to an oxygen (S=O) and two methyl groups.
- (e) **Structure:** A line-angle drawing of propan-1-ol, with a hydroxyl group (-OH) attached to a three-carbon linear chain.
**Explanation:**
Choose the solvent that would result in the slowest rate for an Sₙ2 reaction, focusing on factors such as polarity and proticity.
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