1. Using resonance structures, account for the following phenomenon: a. A normal barrier to rotation for a C=C double bond is about 65 kcal/mol (i.e., the pi bond needs to break to allow free rotation about the remaining single bond). Explain then the abnormally low energy barrier to rotation about the carbon-carbon double bond observed for the following compound: H- H H N(Me)2 AG= 14.6 kcal/mol
1. Using resonance structures, account for the following phenomenon: a. A normal barrier to rotation for a C=C double bond is about 65 kcal/mol (i.e., the pi bond needs to break to allow free rotation about the remaining single bond). Explain then the abnormally low energy barrier to rotation about the carbon-carbon double bond observed for the following compound: H- H H N(Me)2 AG= 14.6 kcal/mol
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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