1. Using resonance structures, account for the following phenomenon: a. A normal barrier to rotation for a C=C double bond is about 65 kcal/mol (i.e., the pi bond needs to break to allow free rotation about the remaining single bond). Explain then the abnormally low energy barrier to rotation about the carbon-carbon double bond observed for the following compound: H- H H N(Me)2 AG= 14.6 kcal/mol
1. Using resonance structures, account for the following phenomenon: a. A normal barrier to rotation for a C=C double bond is about 65 kcal/mol (i.e., the pi bond needs to break to allow free rotation about the remaining single bond). Explain then the abnormally low energy barrier to rotation about the carbon-carbon double bond observed for the following compound: H- H H N(Me)2 AG= 14.6 kcal/mol
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![1. Using resonance structures, account for the following phenomenon:
a. A normal barrier to rotation for a C=C double bond is about 65 kcal/mol (i.e., the pi bond needs to
break to allow free rotation about the remaining single bond). Explain then the abnormally low energy
barrier to rotation about the carbon-carbon double bond observed for the following compound:
H-
H
H
N(Me)2
AG= 14.6 kcal/mol](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F82707a3d-c31e-4fd1-98ca-b785bb827b1c%2F34143366-1e8b-4517-b015-404ea33672bc%2F28ymjls_processed.jpeg&w=3840&q=75)
Transcribed Image Text:1. Using resonance structures, account for the following phenomenon:
a. A normal barrier to rotation for a C=C double bond is about 65 kcal/mol (i.e., the pi bond needs to
break to allow free rotation about the remaining single bond). Explain then the abnormally low energy
barrier to rotation about the carbon-carbon double bond observed for the following compound:
H-
H
H
N(Me)2
AG= 14.6 kcal/mol
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