1. Three of the following five molecules gave rise to the three IR spectra shown below and on the next page. a. Next to the structures, indicate the expected IR peaks for the FGs. b. Match each spectrum to the molecule that produced it. Briefly justify each answer. но 22 23 24 25 26 27 28 29 3 NEAT 22 23 24 25 26 27 28 29 3 NEAT 22 23 24 25 26 27 28 29 3 NUJOL :0: HO MICRONS Jurining 3.5 M 1800 WAVENUMBERS MICRONS (continued on the back) 1600 WAVENUMBERS HO MICRONS :0: WAVENUMBERS H N H3CO 11 :0: :Ö: 12 13 14 15 16 17 18 19 21 23 25 12 -0.4 -2.0 400 NICOLET 205X FT-IR 14 15 16 17 18 19 21 23 25 www. 12 13 14 15 16 17 18 19 04 -88 NICOLET 20SX FT-IR -2.0 HOI 21 23 25 M-04 NICOLET 20SX FT-IR

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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1. Three of the following five molecules gave rise to the three IR spectra shown below and
on the next page.
a. Next to the structures, indicate the expected IR peaks for the FGs.
b. Match each spectrum to the molecule that produced it. Briefly justify each answer.
но
22 23 24 25 26 27 28 29 3
NEAT
2,2 2,3 2,4 25 26 27 28 29 3
NEAT
23 24 25 26 27 28 29 3
:0:
NUJOL
:ỗ:
но
winng
M
HO
2000
1800
WAVENUMBERS
1800
(continued on the back)
MICRONS
WAVENUMBERS
HO
MICRONS
:0:
WAVENUMBERS
H H3CO
:0:
11
:O:
12 13 14 15 16 17 18 19 21 23 25
12 13 14 15 16 17 18 19 21 23 25
ww
wr
12
14
NICOLET 205X FT-IR
AL0₂
15 16 17 18 19
-03
-0.4
-0.6
800
400
NICOLET 20SX FT-IR
21 23 25
HO
-0.3
-0.6
-0.7
-2.0
NICOLET 20SX FT-IR
Transcribed Image Text:1. Three of the following five molecules gave rise to the three IR spectra shown below and on the next page. a. Next to the structures, indicate the expected IR peaks for the FGs. b. Match each spectrum to the molecule that produced it. Briefly justify each answer. но 22 23 24 25 26 27 28 29 3 NEAT 2,2 2,3 2,4 25 26 27 28 29 3 NEAT 23 24 25 26 27 28 29 3 :0: NUJOL :ỗ: но winng M HO 2000 1800 WAVENUMBERS 1800 (continued on the back) MICRONS WAVENUMBERS HO MICRONS :0: WAVENUMBERS H H3CO :0: 11 :O: 12 13 14 15 16 17 18 19 21 23 25 12 13 14 15 16 17 18 19 21 23 25 ww wr 12 14 NICOLET 205X FT-IR AL0₂ 15 16 17 18 19 -03 -0.4 -0.6 800 400 NICOLET 20SX FT-IR 21 23 25 HO -0.3 -0.6 -0.7 -2.0 NICOLET 20SX FT-IR
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