1. The following temperature-composition data were obtained for a mixture of octane (O) and methylbenzene (M) at 760 Torr, where X is the mole fraction in the liquid and Y is the mole in the vapor at equilibrium. T, °C 110.9 112.0 114.0 115.8 117.3 119.0 121.1 123.0 Хм 0.908 0.795 0.615 0.527 0.408 0.300 0.203 0.097 YM 0.923 0.836 0.698 0.624 0.527 0.410 0.297 0.164 The boiling points are 110.60C and 125.60C for M and O, respectively. (a) Plot the temperature-composition diagram for the mixture. (b) What is the composition of the vapor in equilibrium with the liquid of composition XM = 0.250.

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1. The following temperature-composition data were obtained for a mixture of octane (O)
and methylbenzene (M) at 760 ToIT, where X is the mole fraction in the liquid and Y is
the mole in the vapor at equilibrium.
T, °C
110.9
112.0
114.0
115.8
117.3
119.0
121.1
123.0
Хм
0.908
0.795
0.615
0.527
0.408
0.300
0.203
0.097
YM
0.923
0.836
0.698
0.624
0.527
0.410
0.297
0.164
The boiling points are 110.60C and 125.60C for M and O, respectively.
(a) Plot the temperature-composition diagram for the mixture.
(b) What is the composition of the vapor in equilibrium with the liquid of composition
XM = 0.250.
Transcribed Image Text:1. The following temperature-composition data were obtained for a mixture of octane (O) and methylbenzene (M) at 760 ToIT, where X is the mole fraction in the liquid and Y is the mole in the vapor at equilibrium. T, °C 110.9 112.0 114.0 115.8 117.3 119.0 121.1 123.0 Хм 0.908 0.795 0.615 0.527 0.408 0.300 0.203 0.097 YM 0.923 0.836 0.698 0.624 0.527 0.410 0.297 0.164 The boiling points are 110.60C and 125.60C for M and O, respectively. (a) Plot the temperature-composition diagram for the mixture. (b) What is the composition of the vapor in equilibrium with the liquid of composition XM = 0.250.
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Why does in a distillation, it is needed to heat up the mixture above the boiling point of one compound but below the other compound that have a high boiling point?

Follow up question: What happens when you heat the mixture above the boiling point of the two compounds?

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