1. The electrochemical cell, Ag(s)|AGCI(s)| KCI(aq) ||AGNO3(aq) | Ag(s), is constructed to determine the thermodynamic functions AH, AS and AG. The emf values of the cell were measured at several temperatures and the following data were obtained: (Show the data on the graph clearly. Graphs where the data is not properly marked and the related calculations will not be accepted. Show your all calculations on the graph.) Temperature / °C 25 30 35 40 E/ mV 460 456 451 447 (a) Calculate the Gibbs energy change (AG) for the cell at 298 K. (b) Determine the entropy change (AS) by drawing the related graph. (c) Calculate the enthalpy change (AH) for the cell at 298 K. R=8.314 J/mol.K, 1F=96485 C/mol, 1V= 1J/C

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Chapter1: Chemical Foundations
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1. The electrochemical cell, Ag(s)|A9CI(s)|KCI(aq) || AGNO3(aq) | Ag(s), is constructed
to determine the thermodynamic functions AH, AS and AG. The emf values of the cell
were measured at several temperatures and the following data were obtained:
(Show the data on the graph clearly. Graphs where the data is not properly marked and the
related calculations will not be accepted. Show your all calculations on the graph.)
Temperature / °C
25
30
35
40
E/ mV
460
456
451
447
(a) Calculate the Gibbs energy change (AG) for the cell at 298 K.
(b) Determine the entropy change (AS) by drawing the related graph.
(c) Calculate the enthalpy change (AH) for the cell at 298 K.
R=8.314 J/mol.K, 1F=96485 C/mol, 1V= 1J/C
Transcribed Image Text:1. The electrochemical cell, Ag(s)|A9CI(s)|KCI(aq) || AGNO3(aq) | Ag(s), is constructed to determine the thermodynamic functions AH, AS and AG. The emf values of the cell were measured at several temperatures and the following data were obtained: (Show the data on the graph clearly. Graphs where the data is not properly marked and the related calculations will not be accepted. Show your all calculations on the graph.) Temperature / °C 25 30 35 40 E/ mV 460 456 451 447 (a) Calculate the Gibbs energy change (AG) for the cell at 298 K. (b) Determine the entropy change (AS) by drawing the related graph. (c) Calculate the enthalpy change (AH) for the cell at 298 K. R=8.314 J/mol.K, 1F=96485 C/mol, 1V= 1J/C
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