1. The decomposition of aqueous sucrose to form the isomers glucose and fructose is a common organic reaction, which requires a strong catalyst: C12H22O11(aq) + H2O(l) → 2C6H12O6(aq). The following data were collected during the process:Time (min)[C12H22O11] (mol/L)00.316390.274800.2381400.1902100.146(a) If we performed a new trial with an initial concentration of sucrose of 0.400 mol/L, what concentration would remain after 4.0 h has passed?2. Methyl isomerizes to acetonitrile, CH3NC(g) → CH3CN(g) at 215°C. The following data were collected during the process:Time (sec)[CH3NC] (mol/L)20000.011050000.005980000.0031120000.0014150000.00072. (a) Assuming the process continues, what concentration of methyl isonitrile would we expect after 5.00 h?

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Introduction to Chemical Engineering Thermodynamics

8th Edition

ISBN:9781259696527

Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Chapter1: Introduction

Section: Chapter Questions

Problem 1.1P

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1. The decomposition of aqueous sucrose to form the isomers glucose and fructose is a common organic reaction, which requires a strong catalyst: C12H22O11(aq) + H2O(l) → 2C6H12O6(aq). The following data were collected during the process:

Time (min)	[C12H22O11] (mol/L)
0	0.316
39	0.274
80	0.238
140	0.190
210	0.146

(a) If we performed a new trial with an initial concentration of sucrose of 0.400 mol/L, what concentration would remain after 4.0 h has passed?

2. Methyl isomerizes to acetonitrile, CH3NC(g) → CH3CN(g) at 215°C. The following data were collected during the process:

Time (sec)	[CH3NC] (mol/L)
2000	0.0110
5000	0.0059
8000	0.0031
12000	0.0014
15000	0.0007

2. (a) Assuming the process continues, what concentration of methyl isonitrile would we expect after 5.00 h?

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