1. Sketch the MO diagram for HCO3- a. Draw the Lewis structure and count the number of valence electrons b. Assign hybridization of all the atoms i. Determine hybridization of the center atom(s) c. Identify and sketch o-framework i. Identify number ofo bonds in the molecule and the number of e-involved ii. Identify number of lone pairs and the number of e involved d. Identify π framework (Is it localized or delocalized? How many π bonds?) Hint Decide which atoms can participate in r bonds. i. Determine the number of electrons involved in the π bonds ii. Count the p AOs not involved in hybridization e. Sketch the corresponding π MO and corresponding energy diagram for just T-framework. i. Rank them in terms of increasing energy (depending on number ofloops) ii. Fill the t MO's with the electrons involving in t bonds ii. Label the t MO's as bonding, antibonding and/or nonbonding
1. Sketch the MO diagram for HCO3- a. Draw the Lewis structure and count the number of valence electrons b. Assign hybridization of all the atoms i. Determine hybridization of the center atom(s) c. Identify and sketch o-framework i. Identify number ofo bonds in the molecule and the number of e-involved ii. Identify number of lone pairs and the number of e involved d. Identify π framework (Is it localized or delocalized? How many π bonds?) Hint Decide which atoms can participate in r bonds. i. Determine the number of electrons involved in the π bonds ii. Count the p AOs not involved in hybridization e. Sketch the corresponding π MO and corresponding energy diagram for just T-framework. i. Rank them in terms of increasing energy (depending on number ofloops) ii. Fill the t MO's with the electrons involving in t bonds ii. Label the t MO's as bonding, antibonding and/or nonbonding
Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Chapter8: Advanced Theories Of Covalent Bonding
Section: Chapter Questions
Problem 19E: Strike-anywhere matches contain a layer of KClO3 and a layer of P4S3. The heat produced by the...
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