1. Please determine K-C,H., and 50 C and 150 kPa via (a) the DePriester Charts and (b) Raoult's Law w/ Antoine's Eq. 2181.79 In(P kPa) = 13.8254 – t + 248.870 Selected Antoine Coefficients Adapted from Introductory Chemical Engineering Thermodynamics, J. Richard Elliott and Carl T. Lira, Prentice Hall, New York, 2012 Antoine's Equation: log1o(P [mmHg])=A-B/(T["C]+C) tMin["C] tMax["C] methanol ethanol 8.0810 1582.3 18 93 239.7 15 8.1122 1592.9 226.2 1-propanol 1-propanol 2-propanol 7.7442 1437.7 198.5 09 -15 901 98 1788.0 2010.3 227.4 06LE8 8.8783 252.6 1-butanol 97- 7.8103 1522.6 192.0 1-butanol 02 7.7533 1506.1 191.6 1-butanol 02 7.3637 1305.2 173.4 126 68 2-butanol 7.2013 1157.0 168.3 1-octanol LOI 099E 7.2516 2170.2 205.9 ethylene glycol 1448.6 134.1 08 -182 methane 6.6438 395.7 266.7 -158 ethane 6.8292 663.7 L'95 -143 propane n-butane 18- -35.65 6.8034 804.0 247.0 801- -78 6.8078 935.8 238.8 61 58 1064.8 1075.8 n-pentane 6.8530 232.0 n-pentane 6.8763 233.2 0S- -25 n-hexane 89 6.8760 1171.2 224.4 hexane 1189.6 226.3 9016'9 08- n-heptane heptane 1264.9 1264.4 216.5 123 8968°9 7- 6.8939 216.6 127 E- n-octane 1352.0 209.2 152 2816°9 61 n-nonane 6.9389 1431.8 202.1 178 68 n-decane 6.9436 1495.2 193.9 203 89 decane 1843.1 1434.1 230.2 174 LI cyclohexane cyclohexane methyleyelohexane 7.2648 80.7 L'9 L'9 6.8515 1206.5 223.1 18 7.1161 1444.6 240.2 -3 00L 93 8.1122 1592.9 isopentane toluene 226.2 07 17- 6.9509 1342.3 219.2 benzene 6.8799 1196.8 219.2 08 166 m-xylene 0-xylene p-xylene 1600 2 7.0015 1462.3 215.1 67 1476.4 213.9 145 1453.4 215.3 S066'9 991 acetone 7.6313 1566.7 273.4 acetone 7.1171 1210.6 229.7 -13 55 acrolein ethyl acetate 1,4-dioxane 2-butanone 1205.0 235.4 53 6990'2 c9- 7.1018 1245.0 217.9 240.3 246.5 92 105 91 7.4316 1554.7 07 -6.5 7.2807 1434.2 08 2-butanone 7.0636 1261.3 222.0 43 88 3-pentanone 7.2306 1477.0 237.5 water 8.0713 1730.6 233.4 00 82 acetonitrile 1482.3 250.5 66EE'L L7- Triethylamine acetic acid acetic acid chloroform dichloromethane 5.8588 8.0210 695.7 09 81 144.8 95 1936.0 258.5 118 8.2674 2258.2 301.0 227 811 6.9547 226.2 O'ILIT 09 1138.9 01- 231.5 E080'2 69 dichoromethane 7.4092 1325.9 252.6 Ot- tetrachloromethane 6.8409 220.6 6'2L11 07- 1,2-dichloroethane LL 7.0253 1271.3 222.9 IE- 66 Benzyl chloride nitroethane 7.5972 1961.5 236.5 081 7.1946 1446.5 220.8 1.5 16 Biphenyl Naphthalene 13.5354 4993.4 ['967 198.3 07 8.6223 2165.7 07
1. Please determine K-C,H., and 50 C and 150 kPa via (a) the DePriester Charts and (b) Raoult's Law w/ Antoine's Eq. 2181.79 In(P kPa) = 13.8254 – t + 248.870 Selected Antoine Coefficients Adapted from Introductory Chemical Engineering Thermodynamics, J. Richard Elliott and Carl T. Lira, Prentice Hall, New York, 2012 Antoine's Equation: log1o(P [mmHg])=A-B/(T["C]+C) tMin["C] tMax["C] methanol ethanol 8.0810 1582.3 18 93 239.7 15 8.1122 1592.9 226.2 1-propanol 1-propanol 2-propanol 7.7442 1437.7 198.5 09 -15 901 98 1788.0 2010.3 227.4 06LE8 8.8783 252.6 1-butanol 97- 7.8103 1522.6 192.0 1-butanol 02 7.7533 1506.1 191.6 1-butanol 02 7.3637 1305.2 173.4 126 68 2-butanol 7.2013 1157.0 168.3 1-octanol LOI 099E 7.2516 2170.2 205.9 ethylene glycol 1448.6 134.1 08 -182 methane 6.6438 395.7 266.7 -158 ethane 6.8292 663.7 L'95 -143 propane n-butane 18- -35.65 6.8034 804.0 247.0 801- -78 6.8078 935.8 238.8 61 58 1064.8 1075.8 n-pentane 6.8530 232.0 n-pentane 6.8763 233.2 0S- -25 n-hexane 89 6.8760 1171.2 224.4 hexane 1189.6 226.3 9016'9 08- n-heptane heptane 1264.9 1264.4 216.5 123 8968°9 7- 6.8939 216.6 127 E- n-octane 1352.0 209.2 152 2816°9 61 n-nonane 6.9389 1431.8 202.1 178 68 n-decane 6.9436 1495.2 193.9 203 89 decane 1843.1 1434.1 230.2 174 LI cyclohexane cyclohexane methyleyelohexane 7.2648 80.7 L'9 L'9 6.8515 1206.5 223.1 18 7.1161 1444.6 240.2 -3 00L 93 8.1122 1592.9 isopentane toluene 226.2 07 17- 6.9509 1342.3 219.2 benzene 6.8799 1196.8 219.2 08 166 m-xylene 0-xylene p-xylene 1600 2 7.0015 1462.3 215.1 67 1476.4 213.9 145 1453.4 215.3 S066'9 991 acetone 7.6313 1566.7 273.4 acetone 7.1171 1210.6 229.7 -13 55 acrolein ethyl acetate 1,4-dioxane 2-butanone 1205.0 235.4 53 6990'2 c9- 7.1018 1245.0 217.9 240.3 246.5 92 105 91 7.4316 1554.7 07 -6.5 7.2807 1434.2 08 2-butanone 7.0636 1261.3 222.0 43 88 3-pentanone 7.2306 1477.0 237.5 water 8.0713 1730.6 233.4 00 82 acetonitrile 1482.3 250.5 66EE'L L7- Triethylamine acetic acid acetic acid chloroform dichloromethane 5.8588 8.0210 695.7 09 81 144.8 95 1936.0 258.5 118 8.2674 2258.2 301.0 227 811 6.9547 226.2 O'ILIT 09 1138.9 01- 231.5 E080'2 69 dichoromethane 7.4092 1325.9 252.6 Ot- tetrachloromethane 6.8409 220.6 6'2L11 07- 1,2-dichloroethane LL 7.0253 1271.3 222.9 IE- 66 Benzyl chloride nitroethane 7.5972 1961.5 236.5 081 7.1946 1446.5 220.8 1.5 16 Biphenyl Naphthalene 13.5354 4993.4 ['967 198.3 07 8.6223 2165.7 07
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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