1. Please determine K-C,H., and 50 C and 150 kPa via (a) the DePriester Charts and (b) Raoult's Law w/ Antoine's Eq. 2181.79 In(P kPa) = 13.8254 – t + 248.870 Selected Antoine Coefficients Adapted from Introductory Chemical Engineering Thermodynamics, J. Richard Elliott and Carl T. Lira, Prentice Hall, New York, 2012 Antoine's Equation: log1o(P [mmHg])=A-B/(T["C]+C) tMin["C] tMax["C] methanol ethanol 8.0810 1582.3 18 93 239.7 15 8.1122 1592.9 226.2 1-propanol 1-propanol 2-propanol 7.7442 1437.7 198.5 09 -15 901 98 1788.0 2010.3 227.4 06LE8 8.8783 252.6 1-butanol 97- 7.8103 1522.6 192.0 1-butanol 02 7.7533 1506.1 191.6 1-butanol 02 7.3637 1305.2 173.4 126 68 2-butanol 7.2013 1157.0 168.3 1-octanol LOI 099E 7.2516 2170.2 205.9 ethylene glycol 1448.6 134.1 08 -182 methane 6.6438 395.7 266.7 -158 ethane 6.8292 663.7 L'95 -143 propane n-butane 18- -35.65 6.8034 804.0 247.0 801- -78 6.8078 935.8 238.8 61 58 1064.8 1075.8 n-pentane 6.8530 232.0 n-pentane 6.8763 233.2 0S- -25 n-hexane 89 6.8760 1171.2 224.4 hexane 1189.6 226.3 9016'9 08- n-heptane heptane 1264.9 1264.4 216.5 123 8968°9 7- 6.8939 216.6 127 E- n-octane 1352.0 209.2 152 2816°9 61 n-nonane 6.9389 1431.8 202.1 178 68 n-decane 6.9436 1495.2 193.9 203 89 decane 1843.1 1434.1 230.2 174 LI cyclohexane cyclohexane methyleyelohexane 7.2648 80.7 L'9 L'9 6.8515 1206.5 223.1 18 7.1161 1444.6 240.2 -3 00L 93 8.1122 1592.9 isopentane toluene 226.2 07 17- 6.9509 1342.3 219.2 benzene 6.8799 1196.8 219.2 08 166 m-xylene 0-xylene p-xylene 1600 2 7.0015 1462.3 215.1 67 1476.4 213.9 145 1453.4 215.3 S066'9 991 acetone 7.6313 1566.7 273.4 acetone 7.1171 1210.6 229.7 -13 55 acrolein ethyl acetate 1,4-dioxane 2-butanone 1205.0 235.4 53 6990'2 c9- 7.1018 1245.0 217.9 240.3 246.5 92 105 91 7.4316 1554.7 07 -6.5 7.2807 1434.2 08 2-butanone 7.0636 1261.3 222.0 43 88 3-pentanone 7.2306 1477.0 237.5 water 8.0713 1730.6 233.4 00 82 acetonitrile 1482.3 250.5 66EE'L L7- Triethylamine acetic acid acetic acid chloroform dichloromethane 5.8588 8.0210 695.7 09 81 144.8 95 1936.0 258.5 118 8.2674 2258.2 301.0 227 811 6.9547 226.2 O'ILIT 09 1138.9 01- 231.5 E080'2 69 dichoromethane 7.4092 1325.9 252.6 Ot- tetrachloromethane 6.8409 220.6 6'2L11 07- 1,2-dichloroethane LL 7.0253 1271.3 222.9 IE- 66 Benzyl chloride nitroethane 7.5972 1961.5 236.5 081 7.1946 1446.5 220.8 1.5 16 Biphenyl Naphthalene 13.5354 4993.4 ['967 198.3 07 8.6223 2165.7 07

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Related questions
Question
De Priester chart values and Antoine Constant table is also attached with the question
1.
Please determine Ki-C,H., and 50 C and 150 kPa via (a) the DePriester Charts and (b) Raoult's Law w/
Antoine's Eq.
2181.79
In(Pt kPa) = 13.8254 -
t + 248.870
Selected Antoine Coefficients
Adapted from Introductory Chemical Engineering Thermodynamics, J. Richard Elliott and
Carl T. Lira, Prentice Hall, New York, 2012
Antoine's Equation: log1o(P"[mmHg])=A-B/(T["C]+C)
tMin["C] tMax["C]
methanol
ethanol
8.0810
8.1122
1582.3
239.7
226.2
18
93
SI
1592.9
1437.7
1-propanol
1-propanol
2-propanol
1-butanol
7.7442
198.5
09
-15
901
98
1788.0
227.4
062E'8
8.8783
2010.3
252.6
97-
7.8103
1522.6
192.0
1-butanol
02
7.7533
1506.1
191.6
1-butanol
7.3637
1305.2
173.4
126
68
2-butanol
1-octanol
7.2013
1157.0
168.3
LOI
099
7.2516
2170.2
205.9
ethylene glycol
1448.6
134.1
08
-182
007
-158
methane
6.6438
395.7
266.7
ethane
6.8292
663.7
256.7
-143
propane
n-butane
18-
-35.65
6.8034
804.0
247.0
801-
6.8078
935.8
238.8
61
58
82-
n-pentane
n-pentane
n-hexane
6.8530
1064.8
1075.8
232.0
0S-
6.8763
233.2
0S-
89
1171.2
224.4
0928'9
76
hexane
1189.6
226.3
02I
123
9016'9
08-
n-heptane
heptane
1264.9
216.5
7-
-3
89689
6.8939
1264.4
216.6
n-octane
1352.0
209.2
152
2816'9
61
n-nonane
6.9389
1431.8
202.1
178
n-decane
68
6.9436
1495.2
193.9
203
decane
89
00t
7.2648
1843.1
1434.1
230.2
174
LI
cyclohexane
cyclohexane
methyleyclohexane
isopentane
246.7
80.7
L'9
6.8515
1206.5
223.1
18
1444.6
240.2
1911'L
00L
8.1122
1592.9
226.2
07
E6
toluene
1342.3
219.2
6096
L7-
benzene
1196.8
219.2
6628'9
08
m-xylene
0-xylene
p-xylene
acetone
1462.3
215.1
67
63
991
145
1600'2
7.0015
1476.4
213.9
1453.4
215.3
991
205
S066'9
L7
7.6313
273.4
L'99S
acetone
229.7
-13
55
ILIT'2
acrolein
1205.0
1245.0
1554.7
235.4
53
6990'L
c9-
ethyl acetate
1,4-dioxane
217.9
91
92
7.4316
240.3
07
-6.5
2-butanone
SOI
1434.2
1261.3
246.5
2087L
08
2-butanone
7.0636
222.0
88
3-pentanone
7.2306
1477.0
237.5
water
1730.6
233.4
001
82
ELLO'8
acetonitrile
7.3399
1482.3
250.5
L7-
Triethylamine
695.7
144.8
09
18
8898'S
acetic acid
8.0210
1936.0
2258.2
258.5
118
acetic acid
chloroform
dichloromethane
8.2674
301.0
227
6.9547
811
226.2
O'ILIT
09
1138.9
231.5
E080'2
69
dichoromethane
7.4092
1325.9
252.6
tetrachloromethane
1177.9
220.6
6018'9
07-
1,2-dichloroethane
7.0253
1271.3
222.9
66
Benzyl chloride
nitroethane
7.5972
1E-
S'1961
1446.5
236.5
081
7.1946
220.8
1.5
16
Biphenyl
Naphthalene
13.5354
4993.4
296.1
07
07
8.6223
2165.7
198.3
Transcribed Image Text:1. Please determine Ki-C,H., and 50 C and 150 kPa via (a) the DePriester Charts and (b) Raoult's Law w/ Antoine's Eq. 2181.79 In(Pt kPa) = 13.8254 - t + 248.870 Selected Antoine Coefficients Adapted from Introductory Chemical Engineering Thermodynamics, J. Richard Elliott and Carl T. Lira, Prentice Hall, New York, 2012 Antoine's Equation: log1o(P"[mmHg])=A-B/(T["C]+C) tMin["C] tMax["C] methanol ethanol 8.0810 8.1122 1582.3 239.7 226.2 18 93 SI 1592.9 1437.7 1-propanol 1-propanol 2-propanol 1-butanol 7.7442 198.5 09 -15 901 98 1788.0 227.4 062E'8 8.8783 2010.3 252.6 97- 7.8103 1522.6 192.0 1-butanol 02 7.7533 1506.1 191.6 1-butanol 7.3637 1305.2 173.4 126 68 2-butanol 1-octanol 7.2013 1157.0 168.3 LOI 099 7.2516 2170.2 205.9 ethylene glycol 1448.6 134.1 08 -182 007 -158 methane 6.6438 395.7 266.7 ethane 6.8292 663.7 256.7 -143 propane n-butane 18- -35.65 6.8034 804.0 247.0 801- 6.8078 935.8 238.8 61 58 82- n-pentane n-pentane n-hexane 6.8530 1064.8 1075.8 232.0 0S- 6.8763 233.2 0S- 89 1171.2 224.4 0928'9 76 hexane 1189.6 226.3 02I 123 9016'9 08- n-heptane heptane 1264.9 216.5 7- -3 89689 6.8939 1264.4 216.6 n-octane 1352.0 209.2 152 2816'9 61 n-nonane 6.9389 1431.8 202.1 178 n-decane 68 6.9436 1495.2 193.9 203 decane 89 00t 7.2648 1843.1 1434.1 230.2 174 LI cyclohexane cyclohexane methyleyclohexane isopentane 246.7 80.7 L'9 6.8515 1206.5 223.1 18 1444.6 240.2 1911'L 00L 8.1122 1592.9 226.2 07 E6 toluene 1342.3 219.2 6096 L7- benzene 1196.8 219.2 6628'9 08 m-xylene 0-xylene p-xylene acetone 1462.3 215.1 67 63 991 145 1600'2 7.0015 1476.4 213.9 1453.4 215.3 991 205 S066'9 L7 7.6313 273.4 L'99S acetone 229.7 -13 55 ILIT'2 acrolein 1205.0 1245.0 1554.7 235.4 53 6990'L c9- ethyl acetate 1,4-dioxane 217.9 91 92 7.4316 240.3 07 -6.5 2-butanone SOI 1434.2 1261.3 246.5 2087L 08 2-butanone 7.0636 222.0 88 3-pentanone 7.2306 1477.0 237.5 water 1730.6 233.4 001 82 ELLO'8 acetonitrile 7.3399 1482.3 250.5 L7- Triethylamine 695.7 144.8 09 18 8898'S acetic acid 8.0210 1936.0 2258.2 258.5 118 acetic acid chloroform dichloromethane 8.2674 301.0 227 6.9547 811 226.2 O'ILIT 09 1138.9 231.5 E080'2 69 dichoromethane 7.4092 1325.9 252.6 tetrachloromethane 1177.9 220.6 6018'9 07- 1,2-dichloroethane 7.0253 1271.3 222.9 66 Benzyl chloride nitroethane 7.5972 1E- S'1961 1446.5 236.5 081 7.1946 220.8 1.5 16 Biphenyl Naphthalene 13.5354 4993.4 296.1 07 07 8.6223 2165.7 198.3
DePriester Chart Values
2 December 2019
Pressure
60 psia
Enter the pressure in psia in Cell F6
Temperature
530PR
Enter the temperature in °R in Cell F7
Species Species #
K
In(K)
a72
a16
app
In(P)
ap2
ap3
a/T2
a16
appln(P)
ap/p2
apa/P
Methane
1
34.942323 3.5536988 -292860
8.2445
-0.8951 4.0943446 59.8465
-1.042577
8.2445
-3.6648478 0.016624
Ethylene
2
10.121341 2.3146462 -600077
7.90595
-0.84677 4.0943446 42.94594
-2.136265
7.90595
-3.4669681 0.0119294
Ethane
3
6.3368083 1.8463752 -687248
7.90694
-0.886
4.0943446 49.02654
-2.446594
7.90694 -3.6275893 0.0136185
7.71725
Propylene
Propane
1.9681902 0.6771144 -970689
-0.87871 4.0943446 47.67624
-3.455637
7.71725 -3.5977415 0.0132434
1.930926 0.6579997 -970689
7.15059
-0.76984 4.0943446
6.90224
-3.455637
7.15059
-3.1519902
0.1150373
Iso-Butane
6
0.8164472 -0.202793 -1166846
7.72668
-0.92213 4.0943446
-4.153955
7.72668
-3.775518
n-Butane
7
0.5722927 -0.558105 -1280557
7.94986
-0.96455 4.0943446
-4.558765
7.94986
-3.9492
Iso-Pentane
8.
0.2213622 -1.507955 -1481583
7.58071
-0.93159 4.0943446
-5.274414
7.58071 -3.8142505
n-Pentane
9.
0.1742748 -1.747122 -1524891
7.33129
-0.89143 4.0943446
-5.42859
7.33129 -3.6498216
n-Hexane
10
0.0589987 -2.83024 -1778901
6.96783
-0.84634 4.0943446
-6.332862
6.96783 -3.4652076
n-Heptane
11
0.0203081 -3.896734 -2013803
6.52914
-0.79543 4.0943446
-7.16911
6.52914
-3.2567645
n-Octane
12
0.0071655 -4.93848
-7646.816 12.48457
-0.73152 4.0943446
-14.42796 12.48457 -2.9950949
n-Nonane
13
0.0021012 -6.165239 -2551040
5.69313
-0.67818 4.0943446
-9.081666
5.69313 -2.7767026
n-Decane
14
0.0005321 -7.538645
-9760.457 13.80354
-0.7147 4.0943446
-18.41596 13.80354 -2.9262281
Transcribed Image Text:DePriester Chart Values 2 December 2019 Pressure 60 psia Enter the pressure in psia in Cell F6 Temperature 530PR Enter the temperature in °R in Cell F7 Species Species # K In(K) a72 a16 app In(P) ap2 ap3 a/T2 a16 appln(P) ap/p2 apa/P Methane 1 34.942323 3.5536988 -292860 8.2445 -0.8951 4.0943446 59.8465 -1.042577 8.2445 -3.6648478 0.016624 Ethylene 2 10.121341 2.3146462 -600077 7.90595 -0.84677 4.0943446 42.94594 -2.136265 7.90595 -3.4669681 0.0119294 Ethane 3 6.3368083 1.8463752 -687248 7.90694 -0.886 4.0943446 49.02654 -2.446594 7.90694 -3.6275893 0.0136185 7.71725 Propylene Propane 1.9681902 0.6771144 -970689 -0.87871 4.0943446 47.67624 -3.455637 7.71725 -3.5977415 0.0132434 1.930926 0.6579997 -970689 7.15059 -0.76984 4.0943446 6.90224 -3.455637 7.15059 -3.1519902 0.1150373 Iso-Butane 6 0.8164472 -0.202793 -1166846 7.72668 -0.92213 4.0943446 -4.153955 7.72668 -3.775518 n-Butane 7 0.5722927 -0.558105 -1280557 7.94986 -0.96455 4.0943446 -4.558765 7.94986 -3.9492 Iso-Pentane 8. 0.2213622 -1.507955 -1481583 7.58071 -0.93159 4.0943446 -5.274414 7.58071 -3.8142505 n-Pentane 9. 0.1742748 -1.747122 -1524891 7.33129 -0.89143 4.0943446 -5.42859 7.33129 -3.6498216 n-Hexane 10 0.0589987 -2.83024 -1778901 6.96783 -0.84634 4.0943446 -6.332862 6.96783 -3.4652076 n-Heptane 11 0.0203081 -3.896734 -2013803 6.52914 -0.79543 4.0943446 -7.16911 6.52914 -3.2567645 n-Octane 12 0.0071655 -4.93848 -7646.816 12.48457 -0.73152 4.0943446 -14.42796 12.48457 -2.9950949 n-Nonane 13 0.0021012 -6.165239 -2551040 5.69313 -0.67818 4.0943446 -9.081666 5.69313 -2.7767026 n-Decane 14 0.0005321 -7.538645 -9760.457 13.80354 -0.7147 4.0943446 -18.41596 13.80354 -2.9262281
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