1. Name the following alkenes, and predict the products of their reaction with (i) KMnO4 in aqueous acid and (ii) KMnO4 in aqueous NaOH: (a) (b)
1. Name the following alkenes, and predict the products of their reaction with (i) KMnO4 in aqueous acid and (ii) KMnO4 in aqueous NaOH: (a) (b)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![and (ii) KMnO4 in aqueous NaOH:
1. Name the following alkenes, and predict the products of their reaction with (i) KMnO4 in aqueous acid
(a)
(b)
2. Draw structures corresponding to the following IUPAC names:
(a) 3-Ethylhept-1-yne (b) 3,5-Dimethylhex-4-en-1-yne
(c) Hepta-1,5-diyne (d) 1-Methylcyclopenta-1,3-diene
(1)
3. Draw and name all the possible pentyne isomers, C5H8.
H
H
Ç-H
[ Pent-1-yne]
(2)
4. Predict the products of the following
ring is inert to all the indicated reagents.)
4
H
4-
(3)
4-C
C = C-4
[3-methylbut -1-4
[Pent-2-yhdioselectivity where relevant. (The aromatic
CH=CH2
Styrene
(a) Styrene+H2
Pd, ?
(c) Styrene+HBr
?
(b) Styrene+Br2 → ?
(d) Styrene+KMnO4
NaOH, H2O
?
5. Suggest structures for alkenes that give the following reaction products. There may be more than one
answer for some cases.
HyPd catalyst
(a) ?
Br₂ in CH2Cl2
(b) ?
HBr
(c) ?
2-Methylhexane
2,3-Dibromo-5-methylhexane
2-Bromo-3-methylheptane
CH3 HO OH
CH3CHCH2CHCHCH2CH3
KMnO4OH
(d) ?
H₂O](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F63e6a07d-9daf-4f3f-bf56-86ed738ffdd3%2F39f7ab5a-a1e2-4f1e-9624-0eec77b4627c%2F29syxbd_processed.jpeg&w=3840&q=75)
Transcribed Image Text:and (ii) KMnO4 in aqueous NaOH:
1. Name the following alkenes, and predict the products of their reaction with (i) KMnO4 in aqueous acid
(a)
(b)
2. Draw structures corresponding to the following IUPAC names:
(a) 3-Ethylhept-1-yne (b) 3,5-Dimethylhex-4-en-1-yne
(c) Hepta-1,5-diyne (d) 1-Methylcyclopenta-1,3-diene
(1)
3. Draw and name all the possible pentyne isomers, C5H8.
H
H
Ç-H
[ Pent-1-yne]
(2)
4. Predict the products of the following
ring is inert to all the indicated reagents.)
4
H
4-
(3)
4-C
C = C-4
[3-methylbut -1-4
[Pent-2-yhdioselectivity where relevant. (The aromatic
CH=CH2
Styrene
(a) Styrene+H2
Pd, ?
(c) Styrene+HBr
?
(b) Styrene+Br2 → ?
(d) Styrene+KMnO4
NaOH, H2O
?
5. Suggest structures for alkenes that give the following reaction products. There may be more than one
answer for some cases.
HyPd catalyst
(a) ?
Br₂ in CH2Cl2
(b) ?
HBr
(c) ?
2-Methylhexane
2,3-Dibromo-5-methylhexane
2-Bromo-3-methylheptane
CH3 HO OH
CH3CHCH2CHCHCH2CH3
KMnO4OH
(d) ?
H₂O
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